Derivation of optical properties of carbonaceous aerosols by monochromated electron energy-loss spectroscopy

Jiangtao Zhu, Peter Crozier, Peter Ercius, James R. Anderson

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Monochromated electron energy-loss spectroscopy (EELS) is employed to determine the optical properties of carbonaceous aerosols from the infrared to the ultraviolet region of the spectrum. It is essential to determine their optical properties to understand their accurate contribution to radiative forcing for climate change. The influence of surface and interface plasmon effects on the accuracy of dielectric data determined from EELS is discussed. Our measurements show that the standard thin film formulation of Kramers-Kronig analysis can be employed to make accurate determination of the dielectric function for carbonaceous particles down to about 40 nm in size. The complex refractive indices of graphitic and amorphous carbon spherules found in the atmosphere were determined over the wavelength range 200-1,200 nm. The graphitic carbon was strongly absorbing black carbon, whereas the amorphous carbon shows a more weakly absorbing brown carbon profile. The EELS approach provides an important tool for exploring the variation in optical properties of atmospheric carbon.

Original languageEnglish (US)
Pages (from-to)748-759
Number of pages12
JournalMicroscopy and Microanalysis
Volume20
Issue number3
DOIs
StatePublished - 2014

Fingerprint

Electron energy loss spectroscopy
Aerosols
aerosols
derivation
Optical properties
energy dissipation
Amorphous carbon
electron energy
optical properties
Carbon
carbon
spectroscopy
Carbon black
Climate change
Refractive index
spherules
Infrared radiation
Thin films
Wavelength
radiative forcing

Keywords

  • black carbon
  • brown carbon
  • carbonaceous aerosols
  • dielectric functions
  • Kramers-Kronig analysis
  • low-loss EELS
  • monochromator
  • optical properties
  • soot

ASJC Scopus subject areas

  • Instrumentation

Cite this

Derivation of optical properties of carbonaceous aerosols by monochromated electron energy-loss spectroscopy. / Zhu, Jiangtao; Crozier, Peter; Ercius, Peter; Anderson, James R.

In: Microscopy and Microanalysis, Vol. 20, No. 3, 2014, p. 748-759.

Research output: Contribution to journalArticle

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AU - Ercius, Peter

AU - Anderson, James R.

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AB - Monochromated electron energy-loss spectroscopy (EELS) is employed to determine the optical properties of carbonaceous aerosols from the infrared to the ultraviolet region of the spectrum. It is essential to determine their optical properties to understand their accurate contribution to radiative forcing for climate change. The influence of surface and interface plasmon effects on the accuracy of dielectric data determined from EELS is discussed. Our measurements show that the standard thin film formulation of Kramers-Kronig analysis can be employed to make accurate determination of the dielectric function for carbonaceous particles down to about 40 nm in size. The complex refractive indices of graphitic and amorphous carbon spherules found in the atmosphere were determined over the wavelength range 200-1,200 nm. The graphitic carbon was strongly absorbing black carbon, whereas the amorphous carbon shows a more weakly absorbing brown carbon profile. The EELS approach provides an important tool for exploring the variation in optical properties of atmospheric carbon.

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