Damp Heat Induced Degradation of Silicon Heterojunction Solar Cells with Cu-Plated Contacts

Joseph Karas, Archana Sinha, Viswa Sai Pavan Buddha, Fang Li, Farhad Moghadam, Govindasamy Tamizhmani, Stuart Bowden, André Augusto

Research output: Contribution to journalArticle

Abstract

Damp heat exposure is one of the most stringent environments for testing the durability of solar cells in packaged modules. Damp heat stresses and induces a variety of degradation modes in solar cells and modules: for example, moisture-induced corrosion of electrodes and interconnections, deterioration of polymeric materials, and/or thermally activated diffusion processes. To screen for these and other potential degradation modes, we subject one-cell modules containing silicon heterojunction (SHJ) solar cells with Cu-plated contacts to extended damp heat tests at 85 °C/85% relative humidity. SHJ cells were laminated with two common encapsulants: ethylene vinyl acetate (EVA) and polyolefin elastomer (POE), and two constructions: glass-backsheet and glass-glass. We observe degradation in all components of solar cell maximum power (PMP): current, voltage, and fill factor, and find evidence of increased carrier recombination and nonideal diode behavior with increasing stress. For glass-backsheet constructions, EVA samples generally degrade more than POE by a factor of approximately 1.5× PMP, and the different encapsulants produce different degradation patterns. Similar trends are observed in glass-glass modules, but to a lesser degree. In a different experiment, we observe a decrease in effective minority carrier lifetime of nonmetallized SHJ precursors measured after damp heat. This implies that some degradation unrelated to the contacts is to be expected and confirms the observation of increasing recombination.

Original languageEnglish (US)
Article number8878168
Pages (from-to)153-158
Number of pages6
JournalIEEE Journal of Photovoltaics
Volume10
Issue number1
DOIs
StatePublished - Jan 2020

Fingerprint

Silicon
Heterojunctions
heterojunctions
Solar cells
solar cells
degradation
Degradation
Glass
heat
glass
silicon
modules
Elastomers
Polyolefins
elastomers
butadiene
acetates
Ethylene
high temperature tests
Carrier lifetime

Keywords

  • Copper (Cu) plated contacts
  • damp heat (DH)
  • encapsulant
  • fill factor (FF)
  • reliability
  • silicon heterojunction (SHJ)

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

Cite this

Karas, J., Sinha, A., Buddha, V. S. P., Li, F., Moghadam, F., Tamizhmani, G., ... Augusto, A. (2020). Damp Heat Induced Degradation of Silicon Heterojunction Solar Cells with Cu-Plated Contacts. IEEE Journal of Photovoltaics, 10(1), 153-158. [8878168]. https://doi.org/10.1109/JPHOTOV.2019.2941693

Damp Heat Induced Degradation of Silicon Heterojunction Solar Cells with Cu-Plated Contacts. / Karas, Joseph; Sinha, Archana; Buddha, Viswa Sai Pavan; Li, Fang; Moghadam, Farhad; Tamizhmani, Govindasamy; Bowden, Stuart; Augusto, André.

In: IEEE Journal of Photovoltaics, Vol. 10, No. 1, 8878168, 01.2020, p. 153-158.

Research output: Contribution to journalArticle

Karas, J, Sinha, A, Buddha, VSP, Li, F, Moghadam, F, Tamizhmani, G, Bowden, S & Augusto, A 2020, 'Damp Heat Induced Degradation of Silicon Heterojunction Solar Cells with Cu-Plated Contacts', IEEE Journal of Photovoltaics, vol. 10, no. 1, 8878168, pp. 153-158. https://doi.org/10.1109/JPHOTOV.2019.2941693
Karas, Joseph ; Sinha, Archana ; Buddha, Viswa Sai Pavan ; Li, Fang ; Moghadam, Farhad ; Tamizhmani, Govindasamy ; Bowden, Stuart ; Augusto, André. / Damp Heat Induced Degradation of Silicon Heterojunction Solar Cells with Cu-Plated Contacts. In: IEEE Journal of Photovoltaics. 2020 ; Vol. 10, No. 1. pp. 153-158.
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