TY - JOUR
T1 - Crystal structure of kanemite, NaHSi2O5·3H2O, from the Aris phonolite, Namibia
AU - Garvie, Laurence
AU - Devouard, Bertrand
AU - Groy, Thomas L.
AU - Cámara, Fernando
AU - Buseck, P R
PY - 1999
Y1 - 1999
N2 - Kanemite was studied by single-crystal X-ray diffraction. The mineral, ideally NaHSi2O5·3H2O, is orthorhombic (space group Pbcn); unit-cell parameters area a = 4.946(3), b = 20.502(15), c = 7.275(3) Å, with Z = 4. The structure is solved and refined to an R value of 0.058 for 825 independent reflections. The arrangement of atoms consists of alternating (010) sheets of corrugated [Si2O4OH](n)(n-) and hydrated Na. The silicate sheets contain six-membered rings of HOSiO3-SiO4 units. Sodium atoms coordinate to six water molecules, forming layers of distorted octahedra. Residual electron densities were located that give reasonable positions for four H atoms. One H is part of a silanol group, and the other three H atoms are associated with water bonded to Na. Bonding between the silicate and Na sheets is through hydrogen bonding from H of the Na layer to O of the silicate sheet.
AB - Kanemite was studied by single-crystal X-ray diffraction. The mineral, ideally NaHSi2O5·3H2O, is orthorhombic (space group Pbcn); unit-cell parameters area a = 4.946(3), b = 20.502(15), c = 7.275(3) Å, with Z = 4. The structure is solved and refined to an R value of 0.058 for 825 independent reflections. The arrangement of atoms consists of alternating (010) sheets of corrugated [Si2O4OH](n)(n-) and hydrated Na. The silicate sheets contain six-membered rings of HOSiO3-SiO4 units. Sodium atoms coordinate to six water molecules, forming layers of distorted octahedra. Residual electron densities were located that give reasonable positions for four H atoms. One H is part of a silanol group, and the other three H atoms are associated with water bonded to Na. Bonding between the silicate and Na sheets is through hydrogen bonding from H of the Na layer to O of the silicate sheet.
UR - http://www.scopus.com/inward/record.url?scp=0033454028&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033454028&partnerID=8YFLogxK
U2 - 10.2138/am-1999-7-820
DO - 10.2138/am-1999-7-820
M3 - Article
AN - SCOPUS:0033454028
SN - 0003-004X
VL - 84
SP - 1170
EP - 1175
JO - American Mineralogist
JF - American Mineralogist
IS - 7-8
ER -