Crystal chemistry of silica-rich barium silicates II: Electron microscopy of barium silicates containing multiple chains

Michael Czank; P R Buseck

doi:10.1524/zkri.1980.0003

Crystal chemistry of silica-rich barium silicates II: Electron microscopy of barium silicates containing multiple chains

Michael Czank, P R Buseck

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The phases containing multiple chains in the series Ba_m + ₁[Si_2mo_5m+1] — those with triple (m = 3), quadruple (m = 4) and quintuple (m = 5) tetrahedral chains — were investigated by high resolution transmission electron microscopy. The resulting images could be correlated with the structures. Variations of the chain multiplicity (m) within single crystals were observed as well as faults in the packing of the multiple chains. The occurrence of sextuple (m = 6) chains suggests, that stable phases with m > 5 could also exist.

Original language	English (US)
Pages (from-to)	19-32
Number of pages	14
Journal	Zeitschrift fur Kristallographie - New Crystal Structures
Volume	153
Issue number	1-2
DOIs	https://doi.org/10.1524/zkri.1980.0003
State	Published - 1980

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Inorganic Chemistry

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abstract = "The phases containing multiple chains in the series Bam + 1[Si2mo5m+1] — those with triple (m = 3), quadruple (m = 4) and quintuple (m = 5) tetrahedral chains — were investigated by high resolution transmission electron microscopy. The resulting images could be correlated with the structures. Variations of the chain multiplicity (m) within single crystals were observed as well as faults in the packing of the multiple chains. The occurrence of sextuple (m = 6) chains suggests, that stable phases with m > 5 could also exist.",

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AB - The phases containing multiple chains in the series Bam + 1[Si2mo5m+1] — those with triple (m = 3), quadruple (m = 4) and quintuple (m = 5) tetrahedral chains — were investigated by high resolution transmission electron microscopy. The resulting images could be correlated with the structures. Variations of the chain multiplicity (m) within single crystals were observed as well as faults in the packing of the multiple chains. The occurrence of sextuple (m = 6) chains suggests, that stable phases with m > 5 could also exist.

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Crystal chemistry of silica-rich barium silicates II: Electron microscopy of barium silicates containing multiple chains

Abstract

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