Cross-conjugated polymers with large two-photon absorption cross-sections for metal ion sensing

Fei Huang, Yanqing Tian, Ching Yi Chen, Yen Ju Cheng, A. Cody Young, Alex K Y Jen

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35 Scopus citations

Abstract

The synthesis and metal ion sensing properties of two new cross-conjugated polymers, poly[(9,9-di-n-hexylfluorene-2,7-diyl)-alt-co-(2-(4-(N,N- (dibutylamino)styryl)benzene)-1,4-diyl)] (P1) and poly[(9,9-di-n-hexylfluorene- 2,7-diyl)-alt-co-(2,5-bis(4- (N,N-(dibutylamino)styryl)benzene)-1,4-diyl)] (P2) are reported. These two polymers show very different sensing characteristics from those observed for linear conjugated polymers. Upon binding with different metal ions, P1 and P2 show clear intensity changes and large shift of their fluorescence emission peaks. This combined response significantly improves their binding selectivity. Moreover, the donor-π-bridge-donor (D-π-D) conjugated side chain motifs on P2 endow it with efficient two-photon absorbing (2PA) property. This allows it to be used in two-photon laser scanning microscopy and sensing.

Original languageEnglish (US)
Pages (from-to)10673-10681
Number of pages9
JournalJournal of Physical Chemistry C
Volume111
Issue number28
DOIs
Publication statusPublished - Jul 19 2007
Externally publishedYes

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Huang, F., Tian, Y., Chen, C. Y., Cheng, Y. J., Young, A. C., & Jen, A. K. Y. (2007). Cross-conjugated polymers with large two-photon absorption cross-sections for metal ion sensing. Journal of Physical Chemistry C, 111(28), 10673-10681. https://doi.org/10.1021/jp0718799