Correction to: Thermochemistry of stoichiometric rare earth oxyfluorides REOF (Journal of the American Ceramic Society, (2022), 105, 2, (1472-1480), 10.1111/jace.18126)

Shuhao Yang, Andre Anderko, Richard E. Riman, Alexandra Navrotsky

Research output: Contribution to journalComment/debatepeer-review

Abstract

CORRECTION We found that the manuscript titled “Thermochemistry of stoichiometric rare earth oxyfluorides REOF” (J Am Ceram Soc. 2022;105:1472–1480) contains a mistake. Specifically, an incorrect value was used as the electron affinity of O to form O2− (ΔH4 in Table S3), leading to wrong lattice energies (−U) of RE2O3 and REOF in Figure 6 and Table S5. Although this mistake affects the absolute values of −U, which are not discussed in the manuscript, it has no effect on the slopes of −U and the conclusions drawn in this paper. 6 FIGURE (Figure presented.) Lattice energies (−U) of RE2O3, REF3 and REOF with differences for the formation of REOF from RE2O3 and REF3 (UD = −U(REOF) + U(RE2O3)/3+ U(REF3)/3) versus ionic radius of RE3+.

Original languageEnglish (US)
JournalJournal of the American Ceramic Society
DOIs
StateAccepted/In press - 2022

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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