Controlling Thin Film Stress and Wrinkling during Perovskite Film Formation

Kevin A. Bush, Nicholas Rolston, Aryeh Gold-Parker, Salman Manzoor, Jakob Hausele, Zhengshan Yu, James A. Raiford, Rongrong Cheacharoen, Zachary Holman, Michael F. Toney, Reinhold H. Dauskardt, Michael D. McGehee

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Significant effort has focused on controlling the deposition of perovskite films to enable uniform films, enabling efficiencies to climb dramatically. However, little attention has been paid to the evolution of thin film stresses during deposition and the consequent effect on film morphology. While a textured surface topology has potential benefits for light scattering, a smooth surface is desirable to enable the pinhole-free deposition of contact layers. We show that the highly textured morphology made by popular antisolvent conversion methods arises due to in-plane compressive stress experienced during the intermediate phase of film formation, where the substrate constrains the film from expanding leading to energy release in the form of wrinkling, resulting in trenches that can be hundreds of nanometers deep with periods of several microns. We demonstrate that the extent of wrinkling is correlated with the rate of film conversion and ultra-smooth films are obtained by slowing the rate of film formation.

Original languageEnglish (US)
JournalACS Energy Letters
DOIs
StateAccepted/In press - Apr 6 2018

Fingerprint

Perovskite
Thin films
perovskite
Compressive stress
Light scattering
Topology
Substrates

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Bush, K. A., Rolston, N., Gold-Parker, A., Manzoor, S., Hausele, J., Yu, Z., ... McGehee, M. D. (Accepted/In press). Controlling Thin Film Stress and Wrinkling during Perovskite Film Formation. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00544

Controlling Thin Film Stress and Wrinkling during Perovskite Film Formation. / Bush, Kevin A.; Rolston, Nicholas; Gold-Parker, Aryeh; Manzoor, Salman; Hausele, Jakob; Yu, Zhengshan; Raiford, James A.; Cheacharoen, Rongrong; Holman, Zachary; Toney, Michael F.; Dauskardt, Reinhold H.; McGehee, Michael D.

In: ACS Energy Letters, 06.04.2018.

Research output: Contribution to journalArticle

Bush, KA, Rolston, N, Gold-Parker, A, Manzoor, S, Hausele, J, Yu, Z, Raiford, JA, Cheacharoen, R, Holman, Z, Toney, MF, Dauskardt, RH & McGehee, MD 2018, 'Controlling Thin Film Stress and Wrinkling during Perovskite Film Formation', ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00544
Bush, Kevin A. ; Rolston, Nicholas ; Gold-Parker, Aryeh ; Manzoor, Salman ; Hausele, Jakob ; Yu, Zhengshan ; Raiford, James A. ; Cheacharoen, Rongrong ; Holman, Zachary ; Toney, Michael F. ; Dauskardt, Reinhold H. ; McGehee, Michael D. / Controlling Thin Film Stress and Wrinkling during Perovskite Film Formation. In: ACS Energy Letters. 2018.
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