TY - JOUR
T1 - Controllable synthesis of bifunctional porous carbon for efficient gas-mixture separation and high-performance supercapacitor
AU - Wang, Jun
AU - Zhang, Peixin
AU - Liu, Lu
AU - Zhang, Yan
AU - Yang, Jiangfeng
AU - Zeng, Zheling
AU - Deng, Shuguang
N1 - Funding Information:
This work was partially supported by the “Thousand Talent” Program of China, National Natural Science Foundation of China (No. 51672186 ), and “Thousand Talent” Program of Jiangxi Province, China. We gratefully acknowledge the use of facilities within the LeRoy Center for Solid State Science and Gold Water Environmental Laboratory at Arizona State University.
Publisher Copyright:
© 2018
PY - 2018/9/15
Y1 - 2018/9/15
N2 - It is notably challenging to fabricate controllable heteroatom-doped porous carbons for both highly effective mixed-gas separation and supercapacitor electrodes. In this work, novel algae-derived nitrogen-containing porous carbons were prepared as bifunctional materials. The pore structure of obtained carbons could be easily tailored by altering activation temperature or porogen/biomass ratio. The as-prepared porous carbon has a very high specific surface area of 1538.7 m2 g−1 and a large pore volume of 0.99 cm3 g−1 with a high N content of 2.77 wt%. As a solid-state adsorbent, the algae-derived carbon has an excellent CO2 adsorption capacity of 5.7 and 3.9 mmol g−1 at 273 and 298 K, respectively. The extraordinarily high CO2/N2, CO2/CH4, and CH4/N2 selectivity are demonstrated by the ideal adsorption solution theory (IAST) calculation and dynamic adsorption breakthrough experiments. As an electroactive material, the porous carbon exhibits outstanding capacitive performance in 6 M KOH aqueous electrolyte, with the specific capacitance of 287.7 and 190.0 F g−1 at 0.2 A g−1 in a three- and two-electrode system, respectively. Furthermore, the obtained carbon shows outstanding rate capability of 79.3% at 10 A g−1 and unprecedented cycling stability with 98% capacitance retention at 10 A g−1 after 8000 cycles as coin cell. This report introduces a biomass-derived and low-cost pathway to design porous carbon materials for efficient solid adsorbents and supercapacitive electrode materials.
AB - It is notably challenging to fabricate controllable heteroatom-doped porous carbons for both highly effective mixed-gas separation and supercapacitor electrodes. In this work, novel algae-derived nitrogen-containing porous carbons were prepared as bifunctional materials. The pore structure of obtained carbons could be easily tailored by altering activation temperature or porogen/biomass ratio. The as-prepared porous carbon has a very high specific surface area of 1538.7 m2 g−1 and a large pore volume of 0.99 cm3 g−1 with a high N content of 2.77 wt%. As a solid-state adsorbent, the algae-derived carbon has an excellent CO2 adsorption capacity of 5.7 and 3.9 mmol g−1 at 273 and 298 K, respectively. The extraordinarily high CO2/N2, CO2/CH4, and CH4/N2 selectivity are demonstrated by the ideal adsorption solution theory (IAST) calculation and dynamic adsorption breakthrough experiments. As an electroactive material, the porous carbon exhibits outstanding capacitive performance in 6 M KOH aqueous electrolyte, with the specific capacitance of 287.7 and 190.0 F g−1 at 0.2 A g−1 in a three- and two-electrode system, respectively. Furthermore, the obtained carbon shows outstanding rate capability of 79.3% at 10 A g−1 and unprecedented cycling stability with 98% capacitance retention at 10 A g−1 after 8000 cycles as coin cell. This report introduces a biomass-derived and low-cost pathway to design porous carbon materials for efficient solid adsorbents and supercapacitive electrode materials.
KW - Bifunctional material
KW - CO capture
KW - Gas-mixture separation
KW - Porous carbon
KW - Supercapacitor electrode
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U2 - 10.1016/j.cej.2018.04.188
DO - 10.1016/j.cej.2018.04.188
M3 - Article
AN - SCOPUS:85046164637
SN - 1385-8947
VL - 348
SP - 57
EP - 66
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
ER -