Conductance and Configuration of Molecular Gold-Water-Gold Junctions under Electric Fields

Limin Xiang, Peng Zhang, Chaoren Liu, Xin He, Haipeng B. Li, Yueqi Li, Zixiao Wang, Joshua Hihath, Seong H. Kim, David N. Beratan, Nongjian Tao

Research output: Contribution to journalArticle

Abstract

Extensive studies have shown that water can mediate electron transfer by forming water bridges. However, the electrical conductance of a single water molecule at room temperature remains unknown. Here, we studied single water molecular junctions via conductance measurements, theoretical analysis, and infrared spectroscopy. We found two states associated with single water molecular conductance, corresponding to two orientations in the molecular junctions. These two states set fundamental limits on water-mediated electron transfer rates. We further switched the orientations via an external electric field and determined the single water dipole moment. Our work provides a molecular-scale foundation to understand water-mediated electron transfer in chemistry and materials science and motivates future investigations of energy transduction at water-electrode interfaces.

Original languageEnglish (US)
Pages (from-to)166-179
Number of pages14
JournalMatter
Volume3
Issue number1
DOIs
StatePublished - Jul 1 2020

Keywords

  • MAP3: Understanding
  • STM break junction
  • electric field-induced switch
  • molecular electronics
  • single molecule conductance
  • water
  • water-mediated electron transfer

ASJC Scopus subject areas

  • Materials Science(all)

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    Xiang, L., Zhang, P., Liu, C., He, X., Li, H. B., Li, Y., Wang, Z., Hihath, J., Kim, S. H., Beratan, D. N., & Tao, N. (2020). Conductance and Configuration of Molecular Gold-Water-Gold Junctions under Electric Fields. Matter, 3(1), 166-179. https://doi.org/10.1016/j.matt.2020.03.023