Compressibility and pressure-induced amorphization of guest-free melanophlogite: An in-situ synchrotron X-ray diffraction study

Hongwu Xu, Jianzhong Zhang, Yusheng Zhao, George D. Guthrie, Donald D. Hickmott, Alexandra Navrotsky

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Melanophlogite, a clathrasil, possesses a framework of corner-linked silica tetrahedra forming framework cavities that can enclose small guest molecules. Synchrotron X-ray diffraction experiments of the guest-free melanophlogite have been conducted at pressures up to 12 GPa and temperatures up to 1473 K. Upon compression at room temperature, melanophlogite gradually lost its crystallinity and became completely X-ray amorphous at ∼8 GPa. The amorphization process was similar to those of denser silica polymorphs, but it reached completion at a much lower pressure (e.g., quartz becomes X-ray amorphous at ∼30 GPa). The decreased amorphization pressure of melanophlogite may be attributed to its lower framework density and the ease of bending of its Si-O-Si linkages, thereby accelerating the collapse of the structure under high pressure. Determination of cell volumes of melanophlogite prior to its amorphization yielded a room-temperature bulk modulus of 26.3 ± 1.7 GPa, which is consistent with the relatively large compressibilities reported for the structurally similar zeolites. When heated at ∼8 GPa, the amorphous phase started to crystallize at 873 K into coesite, the stable silica phase at these pressure and temperature conditions. Thus the occurrence of pressure-induced amorphization in melanophlogite appears to result from the kinetic hindrance to its transformation to the thermodynamically stable coesite.

Original languageEnglish (US)
Pages (from-to)166-173
Number of pages8
JournalAmerican Mineralogist
Volume92
Issue number1
DOIs
StatePublished - Jan 2007
Externally publishedYes

Keywords

  • Clathrasil
  • Compressibility
  • Melanophlogite
  • Pressure-induced amorphization
  • Synchrotron X-ray diffraction

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology

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