Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems

Anselmo Ellas; C. Austen Angell

doi:10.1021/je00051a001

Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems

Anselmo Ellas, C. Austen Angell

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Following a recent study of the contrasting effects of FeCl_4^- versus CrCl_6^3- complex anion formation on the transport properties of solutions containing them, we report a study of the Intermediate cases of MCl_4^2- complex formation (M = Co²⁺Ni²⁺and Cd²⁺). In these cases an Intermediate and unspectacular response is observed, and secondary factors Intercede to produce an apparent contradiction between composition-dependent behavior close to, and far from, the glass transition. The contradictions are resolved by recognizing that, In these Intermediate cases, the predominant effect of complexation is to produce a decrease in liquid “fragility”.

Original language	English (US)
Pages (from-to)	1-5
Number of pages	5
Journal	Journal of Chemical and Engineering Data
Volume	33
Issue number	1
DOIs	https://doi.org/10.1021/je00051a001
State	Published - Sep 1 1988
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Access to Document

10.1021/je00051a001

Cite this

@article{f25a8de0b9bc4cc7a4b244d441209016,

title = "Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems",

abstract = "Following a recent study of the contrasting effects of FeCl4- versus CrCl63- complex anion formation on the transport properties of solutions containing them, we report a study of the Intermediate cases of MCl42- complex formation (M = Co2+Ni2+and Cd2+). In these cases an Intermediate and unspectacular response is observed, and secondary factors Intercede to produce an apparent contradiction between composition-dependent behavior close to, and far from, the glass transition. The contradictions are resolved by recognizing that, In these Intermediate cases, the predominant effect of complexation is to produce a decrease in liquid “fragility”.",

author = "Anselmo Ellas and {Austen Angell}, C.",

year = "1988",

month = sep,

day = "1",

doi = "10.1021/je00051a001",

language = "English (US)",

volume = "33",

pages = "1--5",

journal = "Journal of Chemical & Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems

AU - Ellas, Anselmo

AU - Austen Angell, C.

PY - 1988/9/1

Y1 - 1988/9/1

N2 - Following a recent study of the contrasting effects of FeCl4- versus CrCl63- complex anion formation on the transport properties of solutions containing them, we report a study of the Intermediate cases of MCl42- complex formation (M = Co2+Ni2+and Cd2+). In these cases an Intermediate and unspectacular response is observed, and secondary factors Intercede to produce an apparent contradiction between composition-dependent behavior close to, and far from, the glass transition. The contradictions are resolved by recognizing that, In these Intermediate cases, the predominant effect of complexation is to produce a decrease in liquid “fragility”.

AB - Following a recent study of the contrasting effects of FeCl4- versus CrCl63- complex anion formation on the transport properties of solutions containing them, we report a study of the Intermediate cases of MCl42- complex formation (M = Co2+Ni2+and Cd2+). In these cases an Intermediate and unspectacular response is observed, and secondary factors Intercede to produce an apparent contradiction between composition-dependent behavior close to, and far from, the glass transition. The contradictions are resolved by recognizing that, In these Intermediate cases, the predominant effect of complexation is to produce a decrease in liquid “fragility”.

UR - http://www.scopus.com/inward/record.url?scp=0023846445&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0023846445&partnerID=8YFLogxK

U2 - 10.1021/je00051a001

DO - 10.1021/je00051a001

M3 - Article

AN - SCOPUS:0023846445

SN - 0021-9568

VL - 33

SP - 1

EP - 5

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

IS - 1

ER -

Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this