Complexation and Transport Properties in Binary Glass-Forming Molten Chloride Systems

Anselmo Ellas, C. Austen Angell

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Abstract

Following a recent study of the contrasting effects of FeCl4- versus CrCl63- complex anion formation on the transport properties of solutions containing them, we report a study of the Intermediate cases of MCl42- complex formation (M = Co2+Ni2+and Cd2+). In these cases an Intermediate and unspectacular response is observed, and secondary factors Intercede to produce an apparent contradiction between composition-dependent behavior close to, and far from, the glass transition. The contradictions are resolved by recognizing that, In these Intermediate cases, the predominant effect of complexation is to produce a decrease in liquid “fragility”.

Original languageEnglish (US)
Pages (from-to)1-5
Number of pages5
JournalJournal of Chemical and Engineering Data
Volume33
Issue number1
DOIs
StatePublished - Sep 1 1988

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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