Comparing well-defined manganese, iron, cobalt, and nickel ketone hydrosilylation catalysts

Ryan Trovitch

doi:10.1055/s-0033-1341269

Comparing well-defined manganese, iron, cobalt, and nickel ketone hydrosilylation catalysts

Ryan Trovitch

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

A brief review of manganese-catalyzed hydrosilylation is presented along with a personal account of how the design for the highly active catalyst, ( ^Ph2PPrPDI)Mn, was conceived. The reductive transformations achieved using this catalyst are described and put into further context by comparing the observed activities with those attained for leading late first-row transition-metal catalysts.

Original language	English (US)
Article number	14689
Pages (from-to)	1638-1642
Number of pages	5
Journal	Synlett
Volume	25
Issue number	12
DOIs	https://doi.org/10.1055/s-0033-1341269
State	Published - Jul 2014

Keywords

catalysis
hydrosilylation
ketones
ligands
manganese

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0033-1341269

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abstract = "A brief review of manganese-catalyzed hydrosilylation is presented along with a personal account of how the design for the highly active catalyst, ( Ph2PPrPDI)Mn, was conceived. The reductive transformations achieved using this catalyst are described and put into further context by comparing the observed activities with those attained for leading late first-row transition-metal catalysts.",

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AB - A brief review of manganese-catalyzed hydrosilylation is presented along with a personal account of how the design for the highly active catalyst, ( Ph2PPrPDI)Mn, was conceived. The reductive transformations achieved using this catalyst are described and put into further context by comparing the observed activities with those attained for leading late first-row transition-metal catalysts.

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KW - ketones

KW - ligands

KW - manganese

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Comparing well-defined manganese, iron, cobalt, and nickel ketone hydrosilylation catalysts

Abstract

Keywords

ASJC Scopus subject areas

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