Chemical processing of water-soluble species and formation of secondary organic aerosol in fogs

Hwajin Kim, Sonya Collier, Xinlei Ge, Jianzhong Xu, Yele Sun, Wenqing Jiang, Youliang Wang, Pierre Herckes, Qi Zhang

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A field study on fog chemistry and aqueous-phase processing of aerosol particles was conducted in Fresno, California's San Joaquin Valley (SJV) during wintertime. Fog droplets were collected while interstitial submicron aerosol was characterized in real time using a High Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-AMS). The fog samples were later analyzed using HR-AMS, ion chromatography (IC), and total organic carbon analyzer (TOC). Compared to interstitial aerosol, dissolved solutes in fog waters were composed of higher fractions of ammonium, nitrate, sulfate, methanesulfonic acid, and oxygenated organic compounds, likely due to aqueous formation of secondary species as well as enhanced gas-to-particle partitioning of water-soluble gases under humid conditions. The low-volatility dissolved organic matter in fog water (F-OA) was moderately oxidized with an average oxygen-to-carbon (O/C) ratio of 0.42. The chemical composition of F-OA appeared to be overall similar to that of oxygenated organic component in interstitial aerosol (OOA) and the HR-AMS mass spectra of F-OA and OOA are highly similar (r2 > 0.95). However, there are also significant chemical differences as F-OA appeared to contain a larger fraction of carboxylic functional groups than OOA, indicating enhanced organic acid formation through aqueous-phase reactions. In addition, F-OA was composed of substantially more nitrogen-containing compounds, with an average N/C ratio ∼4 times that of OOA. Most strikingly was that the F-OA spectra showed substantial enhancements of the CxHyN2 + (x ≥ 0; y ≥ 0) ions, which were likely contributed by imidazole- and/or pyrazine-based compounds formed from the aqueous reactions of aldehydes with amino compounds. The results of this study demonstrated that aqueous reactions in atmospheric droplets can significantly modify aerosol composition and contribute to the formation of oxygenated and nitrogen-containing organic compounds in atmospheric aerosol particles. This finding is important for understanding aerosol's effects on human health, air quality, and climate.

Original languageEnglish (US)
Pages (from-to)158-166
Number of pages9
JournalAtmospheric Environment
Volume200
DOIs
StatePublished - Mar 1 2019

Fingerprint

fog
aerosol
water
spectrometer
droplet
chemical
organic nitrogen compound
aerosol composition
ion chromatography
nitrogen compound
ammonium nitrate
aldehyde
organic acid
gas
dissolved organic matter
total organic carbon
functional group
solute
organic compound
air quality

Keywords

  • Aqueous phase reactions
  • Fog chemistry
  • Secondary aerosol formation

ASJC Scopus subject areas

  • Environmental Science(all)
  • Atmospheric Science

Cite this

Chemical processing of water-soluble species and formation of secondary organic aerosol in fogs. / Kim, Hwajin; Collier, Sonya; Ge, Xinlei; Xu, Jianzhong; Sun, Yele; Jiang, Wenqing; Wang, Youliang; Herckes, Pierre; Zhang, Qi.

In: Atmospheric Environment, Vol. 200, 01.03.2019, p. 158-166.

Research output: Contribution to journalArticle

Kim, Hwajin ; Collier, Sonya ; Ge, Xinlei ; Xu, Jianzhong ; Sun, Yele ; Jiang, Wenqing ; Wang, Youliang ; Herckes, Pierre ; Zhang, Qi. / Chemical processing of water-soluble species and formation of secondary organic aerosol in fogs. In: Atmospheric Environment. 2019 ; Vol. 200. pp. 158-166.
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AU - Jiang, Wenqing

AU - Wang, Youliang

AU - Herckes, Pierre

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AB - A field study on fog chemistry and aqueous-phase processing of aerosol particles was conducted in Fresno, California's San Joaquin Valley (SJV) during wintertime. Fog droplets were collected while interstitial submicron aerosol was characterized in real time using a High Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-AMS). The fog samples were later analyzed using HR-AMS, ion chromatography (IC), and total organic carbon analyzer (TOC). Compared to interstitial aerosol, dissolved solutes in fog waters were composed of higher fractions of ammonium, nitrate, sulfate, methanesulfonic acid, and oxygenated organic compounds, likely due to aqueous formation of secondary species as well as enhanced gas-to-particle partitioning of water-soluble gases under humid conditions. The low-volatility dissolved organic matter in fog water (F-OA) was moderately oxidized with an average oxygen-to-carbon (O/C) ratio of 0.42. The chemical composition of F-OA appeared to be overall similar to that of oxygenated organic component in interstitial aerosol (OOA) and the HR-AMS mass spectra of F-OA and OOA are highly similar (r2 > 0.95). However, there are also significant chemical differences as F-OA appeared to contain a larger fraction of carboxylic functional groups than OOA, indicating enhanced organic acid formation through aqueous-phase reactions. In addition, F-OA was composed of substantially more nitrogen-containing compounds, with an average N/C ratio ∼4 times that of OOA. Most strikingly was that the F-OA spectra showed substantial enhancements of the CxHyN2 + (x ≥ 0; y ≥ 0) ions, which were likely contributed by imidazole- and/or pyrazine-based compounds formed from the aqueous reactions of aldehydes with amino compounds. The results of this study demonstrated that aqueous reactions in atmospheric droplets can significantly modify aerosol composition and contribute to the formation of oxygenated and nitrogen-containing organic compounds in atmospheric aerosol particles. This finding is important for understanding aerosol's effects on human health, air quality, and climate.

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