Charge transfer on the nanoscale: Current status

David M. Adams; Louis Brus; Christopher E D Chidsey; Stephen Creager; Carol Creutz; Cherie R. Kagan; Prashant V. Kamat; Marya Lieberman; Stuart Lindsay; Rudolph A. Marcus; Robert M. Metzger; M. E. Michel-Beyerle; John R. Miller; Marshall D. Newton; Debra R. Rolison; Otto Sankey; Kirk S. Schanze; James Yardley; Xiaoyang Zhu

doi:10.1021/jp0268462

Charge transfer on the nanoscale: Current status

David M. Adams, Louis Brus, Christopher E D Chidsey, Stephen Creager, Carol Creutz, Cherie R. Kagan, Prashant V. Kamat, Marya Lieberman, Stuart Lindsay, Rudolph A. Marcus, Robert M. Metzger, M. E. Michel-Beyerle, John R. Miller, Marshall D. Newton, Debra R. Rolison, Otto Sankey, Kirk S. Schanze, James Yardley, Xiaoyang Zhu

Research output: Contribution to journal › Article › peer-review

935 Scopus citations

Abstract

This is the report of a DOE-sponsored workshop organized to discuss the status of our understanding of charge-transfer processes on the nanoscale and to identify research and other needs for progress in nanoscience and nanotechnology. The current status of basic electron-transfer research, both theoretical and experimental, is addressed, with emphasis on the distance-dependent measurements, and we have attempted to integrate terminology and notation of solution electron-transfer kinetics with that of conductance analysis. The interface between molecules or nanoparticles and bulk metals is examined, and new research tools that advance description and understanding of the interface are presented. The present state-of-the-art in molecular electronics efforts is summarized along with future research needs. Finally, novel strategies that exploit nanoscale architectures are presented for enhancing the efficiences of energy conversion based on photochemistry, catalysis, and electrocatalysis principles.

Original language	English (US)
Pages (from-to)	6668-6697
Number of pages	30
Journal	Journal of Physical Chemistry B
Volume	107
Issue number	28
DOIs	https://doi.org/10.1021/jp0268462
State	Published - Jul 17 2003

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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Adams, D. M., Brus, L., Chidsey, C. E. D., Creager, S., Creutz, C., Kagan, C. R., Kamat, P. V., Lieberman, M., Lindsay, S., Marcus, R. A., Metzger, R. M., Michel-Beyerle, M. E., Miller, J. R., Newton, M. D., Rolison, D. R., Sankey, O., Schanze, K. S., Yardley, J., & Zhu, X. (2003). Charge transfer on the nanoscale: Current status. Journal of Physical Chemistry B, 107(28), 6668-6697. https://doi.org/10.1021/jp0268462

Adams, DM, Brus, L, Chidsey, CED, Creager, S, Creutz, C, Kagan, CR, Kamat, PV, Lieberman, M, Lindsay, S, Marcus, RA, Metzger, RM, Michel-Beyerle, ME, Miller, JR, Newton, MD, Rolison, DR, Sankey, O, Schanze, KS, Yardley, J & Zhu, X 2003, 'Charge transfer on the nanoscale: Current status', Journal of Physical Chemistry B, vol. 107, no. 28, pp. 6668-6697. https://doi.org/10.1021/jp0268462

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abstract = "This is the report of a DOE-sponsored workshop organized to discuss the status of our understanding of charge-transfer processes on the nanoscale and to identify research and other needs for progress in nanoscience and nanotechnology. The current status of basic electron-transfer research, both theoretical and experimental, is addressed, with emphasis on the distance-dependent measurements, and we have attempted to integrate terminology and notation of solution electron-transfer kinetics with that of conductance analysis. The interface between molecules or nanoparticles and bulk metals is examined, and new research tools that advance description and understanding of the interface are presented. The present state-of-the-art in molecular electronics efforts is summarized along with future research needs. Finally, novel strategies that exploit nanoscale architectures are presented for enhancing the efficiences of energy conversion based on photochemistry, catalysis, and electrocatalysis principles.",

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AU - Chidsey, Christopher E D

AU - Creager, Stephen

AU - Creutz, Carol

AU - Kagan, Cherie R.

AU - Kamat, Prashant V.

AU - Lieberman, Marya

AU - Lindsay, Stuart

AU - Marcus, Rudolph A.

AU - Metzger, Robert M.

AU - Michel-Beyerle, M. E.

AU - Miller, John R.

AU - Newton, Marshall D.

AU - Rolison, Debra R.

AU - Sankey, Otto

AU - Schanze, Kirk S.

AU - Yardley, James

AU - Zhu, Xiaoyang

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AB - This is the report of a DOE-sponsored workshop organized to discuss the status of our understanding of charge-transfer processes on the nanoscale and to identify research and other needs for progress in nanoscience and nanotechnology. The current status of basic electron-transfer research, both theoretical and experimental, is addressed, with emphasis on the distance-dependent measurements, and we have attempted to integrate terminology and notation of solution electron-transfer kinetics with that of conductance analysis. The interface between molecules or nanoparticles and bulk metals is examined, and new research tools that advance description and understanding of the interface are presented. The present state-of-the-art in molecular electronics efforts is summarized along with future research needs. Finally, novel strategies that exploit nanoscale architectures are presented for enhancing the efficiences of energy conversion based on photochemistry, catalysis, and electrocatalysis principles.

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Charge transfer on the nanoscale: Current status

Abstract

ASJC Scopus subject areas

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