Neubestimmung der ladungsdichte und topologische analyse von β-diboran bei 94 K

Translated title of the contribution: Charge density redetermination and topological anaysis of β-diboran at 94 K

Christian B. Hübschle, Marc Messerschmidt, Dieter Lentz, Peter Luger

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The experimental charge density of β-diborane was redetermined from 1779 reflections measured with MoKα radiation and CCD-area detection at 94(1) K, (sinθ/λ max = 1.11 Å -1. The strongly bent bond paths of the B-Hμ bonds were verified in the gradient vector field of the charge density. A quantitative topological analysis gave no indication for a bond critical point between the two boron atoms in accordance with theoretical calculations.

Translated title of the contributionCharge density redetermination and topological anaysis of β-diboran at 94 K
Original languageGerman
Pages (from-to)1313-1316
Number of pages4
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume630
Issue number8-9
DOIs
StatePublished - Oct 7 2004
Externally publishedYes

Keywords

  • Boranes
  • Boron
  • Charge density
  • X-ray crystal structure

ASJC Scopus subject areas

  • Inorganic Chemistry

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