Carbonaceous materials in the acid residue from the Orgueil carbonaceous chondrite meteorite

Insoluble organic matter (IOM) dominates the HF/HC1 residue of the Orgueil (CI) carbonaceous chondrite meteorite. The IOM is composed primarily of two C-rich particle types. The first has a fluffy texture similar to crumpled tissue paper, and the second type occurs as solid or hollow nanospheres. High-resolution transmission electron microscope (HRTEM) images of the fluffy material show it is poorly ordered, with small, irregularly shaped regions having fringes with 0.34-0.38 nm spacings and locally 0.21 nm cross-fringes. Nanodiamonds occur in the fluffy material. The rounded C-rich particles are common in the residue and their HRTEM images show neither fringes nor nanodiamonds. Both types of carbonaceous materials have a high aromatic component, as revealed by electron energy-loss spectroscopy (EELS), with up to 10 at% substitution by S, N, and O. The average compositions of the fluffy material and nanospheres are C₁₀₀S_1.9N_3.7 O_4.9 and C₁₀₀S_2.4N_5.0 O_3.9, respectively. The structural and chemical heterogeneity of the carbonaceous materials may represent material from multiple sources.