Carbon-cluster formation from polymers caused by MeV-ion impacts and keV-cluster-ion impacts

Chris Diehnelt, M. J. Van Stipdonk, E. A. Schweikert

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

It has been observed that under MeV-ion bombardment of a polymer, such as polycarbonate (PC) or polyvinylidene fluoride (PVDF), large quantities of carbon clusters [Formula Presented] and [Formula Presented] are generated. However, when PC or PVDF is bombarded with keV atomic ions, very few carbon-cluster ions are produced. This different behavior was attributed to the different sputtering/desorption mechanisms for keV- and MeV-ion impacts. Low-energy keV ions deposit their energy into a solid through nuclear stopping, while MeV ions deposit their energy mainly through electronic stopping. The formation of carbon clusters is thought to be facilitated by the high-temperatures and high-energy densities produced in the region nearest the point of MeV-ion impact, the infratrack region. We have observed extensive carbon-cluster formation from PC and PVDF under keV-cluster-ion bombardment. Despite the vastly different velocities of the high- and low-energy projectiles, identical carbon-cluster trends are produced from MeV [Formula Presented] fission fragments and [Formula Presented] projectile impacts on the same target. This leads us to the conclusion that a polyatomic ion impact, which deposits its kinetic energy near the surface, may create a region of high-temperature and high-energy density that is similar to the infratrack of a MeV-ion impact.

Original languageEnglish (US)
Pages (from-to)4470-4474
Number of pages5
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume59
Issue number6
DOIs
StatePublished - Jan 1 1999
Externally publishedYes

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ion impact
carbon
polymers
polycarbonates
vinylidene
fluorides
ions
deposits
stopping
bombardment
projectiles
flux density
energy
fission
kinetic energy
sputtering
desorption
fragments
trends
electronics

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Carbon-cluster formation from polymers caused by MeV-ion impacts and keV-cluster-ion impacts. / Diehnelt, Chris; Van Stipdonk, M. J.; Schweikert, E. A.

In: Physical Review A - Atomic, Molecular, and Optical Physics, Vol. 59, No. 6, 01.01.1999, p. 4470-4474.

Research output: Contribution to journalArticle

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