Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

Nicholas J. Turro, Yuan Cha, Ian R. Gould, Albert Padwa, John R. Gasdaska, Miguel Tomas

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from a silylthioimidate and subsequent dipolar cycloaddition are carried out.

Original languageEnglish (US)
Pages (from-to)4415-4417
Number of pages3
JournalJournal of Organic Chemistry
Volume50
Issue number22
DOIs
StatePublished - Nov 1985
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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