Capture CO2 from Ambient Air Using Nanoconfined Ion Hydration

Xiaoyang Shi, Hang Xiao, Klaus S. Lackner, Xi Chen

Research output: Contribution to journalArticle

  • 22 Citations

Abstract

Water confined in nanoscopic pores is essential in determining the energetics of many physical and chemical systems. Herein, we report a recently discovered unconventional, reversible chemical reaction driven by water quantities in nanopores. The reduction of the number of water molecules present in the pore space promotes the hydrolysis of CO3 2- to HCO3 - and OH-. This phenomenon led to a nano-structured CO2 sorbent that binds CO2 spontaneously in ambient air when the surrounding is dry, while releasing it when exposed to moisture. The underlying mechanism is elucidated theoretically by computational modeling and verified by experiments. The free energy of CO3 2- hydrolysis in nanopores reduces with a decrease of water availability. This promotes the formation of OH-, which has a high affinity to CO2. The effect is not limited to carbonate/bicarbonate, but is extendable to a series of ions. Humidity-driven sorption opens a new approach to gas separation technology. The presence of water confined in nanoscopic pores was shown to control the equilibrium between CO2 and bicarbonate on adsorbent surfaces. This control allowed for facile sequestration of CO2 from the air, and may influence the design of other adsorbent materials.

LanguageEnglish (US)
Pages4026-4029
Number of pages4
JournalAngewandte Chemie - International Edition
Volume55
Issue number12
DOIs
StatePublished - Mar 14 2016

Fingerprint

Carbon Monoxide
Hydration
Ions
Air
Nanopores
Water
Adsorbents
Hydrolysis
Bicarbonates
Sorbents
Free energy
Sorption
Chemical reactions
Carbonates
Atmospheric humidity
Moisture
Availability
Molecules
Gases
Experiments

Keywords

  • air-water interfaces
  • CO capture
  • free energy
  • ion hydration
  • molecular dynamics

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Capture CO2 from Ambient Air Using Nanoconfined Ion Hydration. / Shi, Xiaoyang; Xiao, Hang; Lackner, Klaus S.; Chen, Xi.

In: Angewandte Chemie - International Edition, Vol. 55, No. 12, 14.03.2016, p. 4026-4029.

Research output: Contribution to journalArticle

Shi, Xiaoyang ; Xiao, Hang ; Lackner, Klaus S. ; Chen, Xi. / Capture CO2 from Ambient Air Using Nanoconfined Ion Hydration. In: Angewandte Chemie - International Edition. 2016 ; Vol. 55, No. 12. pp. 4026-4029
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