C-Norcardenolides

T. R. Kasturi; George Pettit; J. Occolowitz

doi:10.1039/C19670000334

C-Norcardenolides

T. R. Kasturi, George Pettit, J. Occolowitz

Research output: Contribution to journal › Article › peer-review

Original language	English (US)
Pages (from-to)	334-335
Number of pages	2
Journal	Chemical Communications (London)
Issue number	7
DOIs	https://doi.org/10.1039/C19670000334
State	Published - 1967

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General Chemistry

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10.1039/C19670000334

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@article{123be849ae85425a870fc54f415b5d9e,

title = "C-Norcardenolides",

author = "Kasturi, {T. R.} and George Pettit and J. Occolowitz",

note = "Funding Information: 120-125{"}/0~1 mm. (sublimation temp.), i.r. (neat), 5.75 (ester), and 5-8 P (COCH,) and n.m.r. 0.94 (19-CH3), 2.05 (3/3-CH3.C0,), 2.14 (CO-CH,), 3.67 (CO,CH,) and 6-08 (3a-H) 8. The mass-spectral fragmentation patterns of (111) and (V) are also in accordance with the structure assigned. The C-12 + C-14 methylene migration1 is in contrast to the usual methyl group migration reported for Westphalen rearrangements' involving the steroid A/B-ring-functions. This work was supported by grants from the Public Health Service and the National Cancer Institute. ",

year = "1967",

doi = "10.1039/C19670000334",

language = "English (US)",

pages = "334--335",

journal = "Chemical Communications (London)",

issn = "0009-241X",

publisher = "Chemical Society",

number = "7",

}

TY - JOUR

T1 - C-Norcardenolides

AU - Kasturi, T. R.

AU - Pettit, George

AU - Occolowitz, J.

N1 - Funding Information: 120-125"/0~1 mm. (sublimation temp.), i.r. (neat), 5.75 (ester), and 5-8 P (COCH,) and n.m.r. 0.94 (19-CH3), 2.05 (3/3-CH3.C0,), 2.14 (CO-CH,), 3.67 (CO,CH,) and 6-08 (3a-H) 8. The mass-spectral fragmentation patterns of (111) and (V) are also in accordance with the structure assigned. The C-12 + C-14 methylene migration1 is in contrast to the usual methyl group migration reported for Westphalen rearrangements' involving the steroid A/B-ring-functions. This work was supported by grants from the Public Health Service and the National Cancer Institute.

PY - 1967

Y1 - 1967

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U2 - 10.1039/C19670000334

DO - 10.1039/C19670000334

M3 - Article

AN - SCOPUS:37049127368

SN - 0009-241X

SP - 334

EP - 335

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 7

ER -

C-Norcardenolides

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