Broad-range modulation of light emission in two-dimensional semiconductors by molecular physisorption gating

Sefaattin Tongay, Jian Zhou, Can Ataca, Jonathan Liu, Jeong Seuk Kang, Tyler S. Matthews, Long You, Jingbo Li, Jeffrey C. Grossman, Junqiao Wu

Research output: Contribution to journalArticle

435 Scopus citations

Abstract

In the monolayer limit, transition metal dichalcogenides become direct-bandgap, light-emitting semiconductors. The quantum yield of light emission is low and extremely sensitive to the substrate used, while the underlying physics remains elusive. In this work, we report over 100 times modulation of light emission efficiency of these two-dimensional semiconductors by physical adsorption of O2 and/or H2O molecules, while inert gases do not cause such effect. The O2 and/or H2O pressure acts quantitatively as an instantaneously reversible "molecular gating" force, providing orders of magnitude broader control of carrier density and light emission than conventional electric field gating. Physi-sorbed O2 and/or H2O molecules electronically deplete n-type materials such as MoS2 and MoSe2, which weakens electrostatic screening that would otherwise destabilize excitons, leading to the drastic enhancement in photoluminescence. In p-type materials such as WSe2, the molecular physisorption results in the opposite effect. Unique and universal in two-dimensional semiconductors, the effect offers a new mechanism for modulating electronic interactions and implementing optical devices.

Original languageEnglish (US)
Pages (from-to)2831-2836
Number of pages6
JournalNano Letters
Volume13
Issue number6
DOIs
StatePublished - Jun 12 2013
Externally publishedYes

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Keywords

  • 2D semiconductors
  • charge transfer
  • excitons
  • molecular physi-sorption
  • optical emission

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

Cite this

Tongay, S., Zhou, J., Ataca, C., Liu, J., Kang, J. S., Matthews, T. S., You, L., Li, J., Grossman, J. C., & Wu, J. (2013). Broad-range modulation of light emission in two-dimensional semiconductors by molecular physisorption gating. Nano Letters, 13(6), 2831-2836. https://doi.org/10.1021/nl4011172