Broad-range modulation of light emission in two-dimensional semiconductors by molecular physisorption gating

Sefaattin Tongay, Jian Zhou, Can Ataca, Jonathan Liu, Jeong Seuk Kang, Tyler S. Matthews, Long You, Jingbo Li, Jeffrey C. Grossman, Junqiao Wu

    Research output: Contribution to journalArticlepeer-review

    485 Scopus citations


    In the monolayer limit, transition metal dichalcogenides become direct-bandgap, light-emitting semiconductors. The quantum yield of light emission is low and extremely sensitive to the substrate used, while the underlying physics remains elusive. In this work, we report over 100 times modulation of light emission efficiency of these two-dimensional semiconductors by physical adsorption of O2 and/or H2O molecules, while inert gases do not cause such effect. The O2 and/or H2O pressure acts quantitatively as an instantaneously reversible "molecular gating" force, providing orders of magnitude broader control of carrier density and light emission than conventional electric field gating. Physi-sorbed O2 and/or H2O molecules electronically deplete n-type materials such as MoS2 and MoSe2, which weakens electrostatic screening that would otherwise destabilize excitons, leading to the drastic enhancement in photoluminescence. In p-type materials such as WSe2, the molecular physisorption results in the opposite effect. Unique and universal in two-dimensional semiconductors, the effect offers a new mechanism for modulating electronic interactions and implementing optical devices.

    Original languageEnglish (US)
    Pages (from-to)2831-2836
    Number of pages6
    JournalNano Letters
    Issue number6
    StatePublished - Jun 12 2013


    • 2D semiconductors
    • charge transfer
    • excitons
    • molecular physi-sorption
    • optical emission

    ASJC Scopus subject areas

    • Bioengineering
    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanical Engineering

    Fingerprint Dive into the research topics of 'Broad-range modulation of light emission in two-dimensional semiconductors by molecular physisorption gating'. Together they form a unique fingerprint.

    Cite this