Arsenic contamination of Bangladesh aquifers exacerbated by clay layers

Ivan Mihajlov, M. Rajib H. Mozumder, Benjamín C. Bostick, Martin Stute, Brian J. Mailloux, Peter S.K. Knappett, Imtiaz Choudhury, Kazi Matin Ahmed, Peter Schlosser, Alexander van Geen

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

Confining clay layers typically protect groundwater aquifers against downward intrusion of contaminants. In the context of groundwater arsenic in Bangladesh, we challenge this notion here by showing that organic carbon drawn from a clay layer into a low-arsenic pre-Holocene (>12 kyr-old) aquifer promotes the reductive dissolution of iron oxides and the release of arsenic. The finding explains a steady rise in arsenic concentrations in a pre-Holocene aquifer below such a clay layer and the repeated failure of a structurally sound community well. Tritium measurements indicate that groundwater from the affected depth interval (40–50 m) was recharged >60 years ago. Deeper (55–65 m) groundwater in the same pre-Holocene aquifer was recharged only 10–50 years ago but is still low in arsenic. Proximity to a confining clay layer that expels organic carbon as an indirect response to groundwater pumping, rather than directly accelerated recharge, caused arsenic contamination of this pre-Holocene aquifer.

Original languageEnglish (US)
Article number2244
JournalNature communications
Volume11
Issue number1
DOIs
StatePublished - Dec 1 2020

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

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    Mihajlov, I., Mozumder, M. R. H., Bostick, B. C., Stute, M., Mailloux, B. J., Knappett, P. S. K., Choudhury, I., Ahmed, K. M., Schlosser, P., & van Geen, A. (2020). Arsenic contamination of Bangladesh aquifers exacerbated by clay layers. Nature communications, 11(1), [2244]. https://doi.org/10.1038/s41467-020-16104-z