Apparatus and method for time-integrated, active sampling of contaminants in fluids demonstrated by monitoring of hexavalent chromium in groundwater

Isaac B. Roll, Erin M. Driver, Rolf Halden

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Annual U.S. expenditures of $2B for site characterization invite the development of new technologies to improve data quality while reducing costs and minimizing uncertainty in groundwater monitoring. This work presents a new instrument for time-integrated sampling of environmental fluids using in situ solid-phase extraction (SPE). The In Situ Sampler (IS2) is an automated submersible device capable of extracting dissolved contaminants from water (100s-1000s mL) over extended periods (hours to weeks), retaining the analytes, and rejecting the processed fluid. A field demonstration of the IS2 revealed 28-day average concentration of hexavalent chromium in a shallow aquifer affected by tidal stresses via sampling of groundwater as both liquid and sorbed composite samples, each obtained in triplicate. In situ SPE exhibited 75 ± 6% recovery and an 8-fold improvement in reporting limit. Relative to use of conventional methods (100%), beneficial characteristics of the device and method included minimal hazardous material generation (2%), transportation cost (10%), and associated carbon footprint (2%). The IS2 is compatible with commercial SPE resins and standard extraction methods, and has been certified for more general use (i.e., inorganics and organics) by the Environmental Security Technology Certification Program (ESTCP) of the U.S. Department of Defense.

Original languageEnglish (US)
Pages (from-to)45-52
Number of pages8
JournalScience of the Total Environment
Volume556
DOIs
StatePublished - Jun 15 2016

Fingerprint

chromium
Groundwater
Chromium
Impurities
Sampling
Fluids
groundwater
fluid
pollutant
Monitoring
sampling
monitoring
carbon footprint
site characterization
submersible
certification
extraction method
Hazardous Substances
data quality
cost

Keywords

  • Active sampling
  • Environmental characterization
  • Hexavalent chromium
  • Solid-phase extraction
  • Time-integrated
  • Water sampling

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution
  • Waste Management and Disposal
  • Environmental Engineering

Cite this

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abstract = "Annual U.S. expenditures of $2B for site characterization invite the development of new technologies to improve data quality while reducing costs and minimizing uncertainty in groundwater monitoring. This work presents a new instrument for time-integrated sampling of environmental fluids using in situ solid-phase extraction (SPE). The In Situ Sampler (IS2) is an automated submersible device capable of extracting dissolved contaminants from water (100s-1000s mL) over extended periods (hours to weeks), retaining the analytes, and rejecting the processed fluid. A field demonstration of the IS2 revealed 28-day average concentration of hexavalent chromium in a shallow aquifer affected by tidal stresses via sampling of groundwater as both liquid and sorbed composite samples, each obtained in triplicate. In situ SPE exhibited 75 ± 6{\%} recovery and an 8-fold improvement in reporting limit. Relative to use of conventional methods (100{\%}), beneficial characteristics of the device and method included minimal hazardous material generation (2{\%}), transportation cost (10{\%}), and associated carbon footprint (2{\%}). The IS2 is compatible with commercial SPE resins and standard extraction methods, and has been certified for more general use (i.e., inorganics and organics) by the Environmental Security Technology Certification Program (ESTCP) of the U.S. Department of Defense.",
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