Analysis of Isomerization in Compounds Displaying Restricted Rotation of Aryl Groups

Devens Gust; Kurt Mislow

doi:10.1021/ja00786a031

Analysis of Isomerization in Compounds Displaying Restricted Rotation of Aryl Groups

Devens Gust, Kurt Mislow

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar₃ZX (e.g., Ar₃CH, Ar₃P) and Ar₃Z (e.g., Ar₃B), and also for the diaryl systems Ar₂ZXY (e.g., Ar₂CHCl, Ar₂PH), Ar₂ZX₂ (e.g., Ar₂CH₂, Ar₂O), and Ar₂ZX (e.g., Ar₂CO, Ar₂O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

Original language	English (US)
Pages (from-to)	1535-1547
Number of pages	13
Journal	Journal of the American Chemical Society
Volume	95
Issue number	5
DOIs	https://doi.org/10.1021/ja00786a031
State	Published - Mar 1 1973

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.",

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N2 - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

AB - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

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Analysis of Isomerization in Compounds Displaying Restricted Rotation of Aryl Groups

Abstract

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