An intermodulated fluorescence study of the A2Σ--X2Πi band system of copper monoxide

Timothy C. Steimle, Yoshiro Azuma

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9 Scopus citations

Abstract

Several lines in the A2Σ-(v = 0)-X2Πi(v = 0) visible band system of gas phase copper monoxide have been measured at sub-Doppler resolution using the technique of intermodulated fluorescence. The copper nuclear magnetic hyperfine splitting is clearly resolved. The observations were fitted to an effective Hamiltonian model and values of the magnetic hyperfine parameters of bF = -0.0302 cm-1 for the A state and d = 0.0024 cm-1 for the X state were determined. An interpretation of these values in terms of the proposed electronic configurations of these states is presented.

Original languageEnglish (US)
Pages (from-to)237-247
Number of pages11
JournalJournal of molecular spectroscopy
Volume118
Issue number1
DOIs
StatePublished - Jul 1986
Externally publishedYes

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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