An Efficient and Reusable Embedded Ru Catalyst for the Hydrogenolysis of Levulinic Acid to γ-Valerolactone

Zuojun Wei, Jiongtao Lou, Chuanmin Su, Dechao Guo, Yingxin Liu, Shuguang Deng

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

To achieve a higher activity and reusability of a Ru-based catalyst, Ru nanoparticles were embedded in N-doped mesoporous carbon through a hard-template method. The catalyst showed excellent catalytic performance (314h-1 turnover frequency) and recyclability (reusable five times with 3% activity loss) for the hydrogenolysis of levulinic acid to γ-valerolactone. Compared with the mesoporous carbon without N-doping and conventional activated carbon, the introduction of N-dopant effectively improved the dispersion of Ru nanoparticles, decreased the average size of Ru nanoparticles to as small as 1.32nm, and improved the adsorption of levulinic acid, which contributed to the increase in the activity of the catalyst. Additionally, the embedding method increased the interaction between Ru nanoparticles and carbon support in contrast with the conventional impregnation method, thus preventing the Ru nanoparticles from migration, aggregation, and leaching from the carbon surface and therefore increasing the reusability of the catalyst.

Original languageEnglish (US)
JournalChemSusChem
DOIs
StateAccepted/In press - 2017

Fingerprint

Hydrogenolysis
catalyst
Nanoparticles
Carbon
Catalysts
Acids
acid
carbon
Reusability
Doping (additives)
Impregnation
Activated carbon
Leaching
activated carbon
turnover
Agglomeration
leaching
levulinic acid
nanoparticle
adsorption

Keywords

  • Embedding method
  • Hydrogenolysis
  • Levulinic acid
  • Ruthenium
  • γ-valerolactone

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

An Efficient and Reusable Embedded Ru Catalyst for the Hydrogenolysis of Levulinic Acid to γ-Valerolactone. / Wei, Zuojun; Lou, Jiongtao; Su, Chuanmin; Guo, Dechao; Liu, Yingxin; Deng, Shuguang.

In: ChemSusChem, 2017.

Research output: Contribution to journalArticle

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AU - Guo, Dechao

AU - Liu, Yingxin

AU - Deng, Shuguang

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N2 - To achieve a higher activity and reusability of a Ru-based catalyst, Ru nanoparticles were embedded in N-doped mesoporous carbon through a hard-template method. The catalyst showed excellent catalytic performance (314h-1 turnover frequency) and recyclability (reusable five times with 3% activity loss) for the hydrogenolysis of levulinic acid to γ-valerolactone. Compared with the mesoporous carbon without N-doping and conventional activated carbon, the introduction of N-dopant effectively improved the dispersion of Ru nanoparticles, decreased the average size of Ru nanoparticles to as small as 1.32nm, and improved the adsorption of levulinic acid, which contributed to the increase in the activity of the catalyst. Additionally, the embedding method increased the interaction between Ru nanoparticles and carbon support in contrast with the conventional impregnation method, thus preventing the Ru nanoparticles from migration, aggregation, and leaching from the carbon surface and therefore increasing the reusability of the catalyst.

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