An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Anuja Sharma; Sangho So; Jun Hyeong Kim; Samantha N. MacMillan; Mu Hyun Baik; Ryan J. Trovitch

doi:10.1039/d2cc04089a

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Anuja Sharma, Sangho So, Jun Hyeong Kim, Samantha N. MacMillan, Mu Hyun Baik, Ryan J. Trovitch

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (^Ph₂PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s⁻¹ is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

Original language	English (US)
Pages (from-to)	10793-10796
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	77
DOIs	https://doi.org/10.1039/d2cc04089a
State	Published - Aug 24 2022

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/d2cc04089a

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title = "An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation",

abstract = "Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.",

author = "Anuja Sharma and Sangho So and Kim, {Jun Hyeong} and MacMillan, {Samantha N.} and Baik, {Mu Hyun} and Trovitch, {Ryan J.}",

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AU - Sharma, Anuja

AU - So, Sangho

AU - Kim, Jun Hyeong

AU - MacMillan, Samantha N.

AU - Baik, Mu Hyun

AU - Trovitch, Ryan J.

PY - 2022/8/24

Y1 - 2022/8/24

N2 - Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

AB - Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

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An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Abstract

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CCDC 2176486: Experimental Crystal Structure Determination

CCDC 2176487: Experimental Crystal Structure Determination

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An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 2176486: Experimental Crystal Structure Determination

CCDC 2176487: Experimental Crystal Structure Determination

Cite this