This study presents a survey of abundance distribution and isotopic composition of the ammonia found incorporated in the kerogen-like insoluble material of selected carbonaceous chondrite meteorites; the ammonia was released upon hydrothermal treatment at 300°C and 100 MPa. With the exception of Allende, a metamorphosed and highly altered stone, all the insoluble organic materials (IOM) of the meteorites analyzed released significant amounts of ammonia, which varied from over 4 μgmg-1 for the Orgueil IOM to 0.5 μgmg-1 for that of Tagish Lake; the IOM of the pristine Antarctica find GRA95229 remains the most rich in freeable ammonia with 10 μgmg-1. While the amounts of IOM bound ammonia do not appear to vary between meteorites with a recognizable trend, a possible consequence of long terrestrial exposure of some of the stones, we found that the δ15N composition of the ammonia-carrying materials is clearly distinctive of meteorite types and may reflect a preservation of the original 15N distribution of pre- and proto-solar materials.
|Original language||English (US)|
|State||Published - Apr 20 2012|
- minor planets, asteroids: general
- molecular data
ASJC Scopus subject areas
- Astronomy and Astrophysics
- Space and Planetary Science