Ag2+ in trigonal-bipyramidaler Umgebung: Neue fluoride mit zweiwertigem silber: AgMa3IIM3IVF20 (MII = Cd, Ca, Hg; MIV = Zr, Hf)

O. Graudejus; B. G. Müller

doi:10.1002/zaac.19966220918

Ag²⁺ in trigonal-bipyramidaler Umgebung: Neue fluoride mit zweiwertigem silber: AgMa₃^IIM₃^IVF₂₀ (M^II = Cd, Ca, Hg; M^IV = Zr, Hf)

Translated title of the contribution: Ag²⁺ in trigonal-bipyramidal surrounding new fluorides with divalent silver AgM₃^IIM₃^IVF₂₀ (M^II = Cd, Ca, Hg; M^IV = Zr, Hf)

O. Graudejus, B. G. Müller

Arizona State University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The intensively green compounds AgM₃^IIM₃^IVF₂₀ (M^II = Cd, Ca, Hg; M^IV = Zr, Hf) have been obtained for the first time as single crystals and investigated by X-ray methods. They crystallize in space group P6₃/m-C_6h² (Nr. 176) with a = 1052.0(2) pm, c = 828.6(2) pm (AgCd₃Zr₃F₂₀), a = 1048.0(2) pm, c = 832.6(3) pm (AgCd₃Hf₃F₂₀), a = 1059.4(2) pm, c = 841.0(3) pm (AgCa₃Zr₃F₂₀), a = 1053.7(2) pm, c = 830.6(3) pm (AgCa₃Hf₃F₂₀), a = 1058.9(3) pm, c = 832.6(4) pm (AgHg₃Zr₃F₂₀), a = 1056.9(2) pm, c = 833.0(3) pm (AgHg₃Hf₃F₂₀), Z = 2.

Translated title of the contribution	Ag²⁺ in trigonal-bipyramidal surrounding new fluorides with divalent silver AgM₃^IIM₃^IVF₂₀ (M^II = Cd, Ca, Hg; M^IV = Zr, Hf)
Original language	German
Pages (from-to)	1549-1556
Number of pages	8
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	622
Issue number	9
DOIs	https://doi.org/10.1002/zaac.19966220918
State	Published - Jan 1 1996

Keywords

Silver(II)-fluorozirconates and -hafnates
Single Crystal Structure

ASJC Scopus subject areas

Inorganic Chemistry

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@article{960bced8cd16459cb1198ceee2cbf9d1,

title = "Ag2+ in trigonal-bipyramidaler Umgebung: Neue fluoride mit zweiwertigem silber: AgMa3IIM3IVF20 (MII = Cd, Ca, Hg; MIV = Zr, Hf)",

abstract = "The intensively green compounds AgM3IIM3IVF20 (MII = Cd, Ca, Hg; MIV = Zr, Hf) have been obtained for the first time as single crystals and investigated by X-ray methods. They crystallize in space group P63/m-C6h2 (Nr. 176) with a = 1052.0(2) pm, c = 828.6(2) pm (AgCd3Zr3F20), a = 1048.0(2) pm, c = 832.6(3) pm (AgCd3Hf3F20), a = 1059.4(2) pm, c = 841.0(3) pm (AgCa3Zr3F20), a = 1053.7(2) pm, c = 830.6(3) pm (AgCa3Hf3F20), a = 1058.9(3) pm, c = 832.6(4) pm (AgHg3Zr3F20), a = 1056.9(2) pm, c = 833.0(3) pm (AgHg3Hf3F20), Z = 2.",

keywords = "Silver(II)-fluorozirconates and -hafnates, Single Crystal Structure",

author = "O. Graudejus and M{\"u}ller, {B. G.}",

year = "1996",

month = jan,

day = "1",

doi = "10.1002/zaac.19966220918",

language = "German",

volume = "622",

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AU - Graudejus, O.

AU - Müller, B. G.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The intensively green compounds AgM3IIM3IVF20 (MII = Cd, Ca, Hg; MIV = Zr, Hf) have been obtained for the first time as single crystals and investigated by X-ray methods. They crystallize in space group P63/m-C6h2 (Nr. 176) with a = 1052.0(2) pm, c = 828.6(2) pm (AgCd3Zr3F20), a = 1048.0(2) pm, c = 832.6(3) pm (AgCd3Hf3F20), a = 1059.4(2) pm, c = 841.0(3) pm (AgCa3Zr3F20), a = 1053.7(2) pm, c = 830.6(3) pm (AgCa3Hf3F20), a = 1058.9(3) pm, c = 832.6(4) pm (AgHg3Zr3F20), a = 1056.9(2) pm, c = 833.0(3) pm (AgHg3Hf3F20), Z = 2.

AB - The intensively green compounds AgM3IIM3IVF20 (MII = Cd, Ca, Hg; MIV = Zr, Hf) have been obtained for the first time as single crystals and investigated by X-ray methods. They crystallize in space group P63/m-C6h2 (Nr. 176) with a = 1052.0(2) pm, c = 828.6(2) pm (AgCd3Zr3F20), a = 1048.0(2) pm, c = 832.6(3) pm (AgCd3Hf3F20), a = 1059.4(2) pm, c = 841.0(3) pm (AgCa3Zr3F20), a = 1053.7(2) pm, c = 830.6(3) pm (AgCa3Hf3F20), a = 1058.9(3) pm, c = 832.6(4) pm (AgHg3Zr3F20), a = 1056.9(2) pm, c = 833.0(3) pm (AgHg3Hf3F20), Z = 2.

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