Aggregation phenomena in lyotropic chromonic liquid crystals

Lidia Mrad, Longhua Zhao, Malena I. Español, Ling Xu, M. Carme Calderer

Research output: Contribution to journalArticlepeer-review

Abstract

We study the aggregation phenomenon in lyotropic chromonic liquid crystals as the molecular concentration changes and condensing agents are added into the system. Using properties of the critical points of the Oseen–Frank energy of a nematic liquid crystal, combined with the geometric constraints of the hexagonal columnar chromonic phases, we show that the minimizers of the total energy are topologically equivalent to tori, in agreement with available experimental evidence on chromonic liquid crystals and DNA condensates, in viral capsids as well as in free solution. We model the system as bi-phasic, consisting of liquid crystal molecules and water, and postulate the total energy as the sum of the Flory–Huggins energy of mixing together with the bending and surface tension contributions of the liquid crystal. Two types of problems are considered, one related to finding the optimal shape of a torus, once the phase separation has occurred, and the second one that models the conditions leading to molecular aggregation. This work follows recent experimental investigations, but without addressing the topological properties of the toroidal nuclei observed and focusing on how the liquid crystal order competes with the aggregation phenomenon.

Original languageEnglish (US)
Article number107139
JournalCommunications in Nonlinear Science and Numerical Simulation
Volume120
DOIs
StatePublished - Jun 2023

Keywords

  • Chromonic liquid crystals
  • Flory–Huggins energy
  • Oseen–Frank energy
  • Toroidal nuclei

ASJC Scopus subject areas

  • Numerical Analysis
  • Modeling and Simulation
  • Applied Mathematics

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