Adiabatic outer sphere electron transfer through the metal-electrolyte interface

A. V. Gorodyskii; A. I. Karasevskii; D. V. Matyushov

doi:10.1016/0022-0728(91)80058-X

Adiabatic outer sphere electron transfer through the metal-electrolyte interface

A. V. Gorodyskii, A. I. Karasevskii, D. V. Matyushov

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A theoretical study of the adiabatic reaction of electron transfer from a metal electrode to an acceptor level in a polar liquid is presented. The Gibbs energy of the electrochemical system along the electron transfer coordinate has been obtained at all values of the overlap of the metal and acceptor electronic states, over a wide range of the electrode overpotentials. The electron transfer probability has been calculated at high and low activation barriers of the reaction.

Original language	English (US)
Pages (from-to)	9-28
Number of pages	20
Journal	Journal of Electroanalytical Chemistry
Volume	315
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(91)80058-X
State	Published - Oct 10 1991
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/0022-0728(91)80058-X

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abstract = "A theoretical study of the adiabatic reaction of electron transfer from a metal electrode to an acceptor level in a polar liquid is presented. The Gibbs energy of the electrochemical system along the electron transfer coordinate has been obtained at all values of the overlap of the metal and acceptor electronic states, over a wide range of the electrode overpotentials. The electron transfer probability has been calculated at high and low activation barriers of the reaction.",

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AU - Matyushov, D. V.

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Y1 - 1991/10/10

N2 - A theoretical study of the adiabatic reaction of electron transfer from a metal electrode to an acceptor level in a polar liquid is presented. The Gibbs energy of the electrochemical system along the electron transfer coordinate has been obtained at all values of the overlap of the metal and acceptor electronic states, over a wide range of the electrode overpotentials. The electron transfer probability has been calculated at high and low activation barriers of the reaction.

AB - A theoretical study of the adiabatic reaction of electron transfer from a metal electrode to an acceptor level in a polar liquid is presented. The Gibbs energy of the electrochemical system along the electron transfer coordinate has been obtained at all values of the overlap of the metal and acceptor electronic states, over a wide range of the electrode overpotentials. The electron transfer probability has been calculated at high and low activation barriers of the reaction.

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Adiabatic outer sphere electron transfer through the metal-electrolyte interface

Abstract

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