Absolute rate constants for the additions of halophenylcarbenes to alkenes: a reactivity-selectivity relation

D. Phillip Cox, Ian Gould, Nigel P. Hacker, Robert A. Moss, Nicholas J. Turro

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The absolute rate constants determined for the additions of FCPh, ClCPh, and BrCPh to Me2C=CMe2, Me2C=CHMe, trans-MeCH=CHEt, and n-BuCH=CH2 appear to follow a reactivity/selectivity pattern of the "normal" (inverse) type.

Original languageEnglish (US)
Pages (from-to)5313-5316
Number of pages4
JournalTetrahedron Letters
Volume24
Issue number48
DOIs
StatePublished - 1983
Externally publishedYes

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Alkenes
Rate constants

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Absolute rate constants for the additions of halophenylcarbenes to alkenes : a reactivity-selectivity relation. / Cox, D. Phillip; Gould, Ian; Hacker, Nigel P.; Moss, Robert A.; Turro, Nicholas J.

In: Tetrahedron Letters, Vol. 24, No. 48, 1983, p. 5313-5316.

Research output: Contribution to journalArticle

Cox, D. Phillip ; Gould, Ian ; Hacker, Nigel P. ; Moss, Robert A. ; Turro, Nicholas J. / Absolute rate constants for the additions of halophenylcarbenes to alkenes : a reactivity-selectivity relation. In: Tetrahedron Letters. 1983 ; Vol. 24, No. 48. pp. 5313-5316.
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