Aberration-corrected scanning transmission electron microscopy study of β′-like precipitates in an Al-Mg-Ge alloy

R. Bjørge, C. Dwyer, M. Weyland, P. N.H. Nakashima, C. D. Marioara, S. J. Andersen, J. Etheridge, R. Holmestad

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

Precipitates in an Al-Mg-Ge alloy similar to the β′ phase in Al-Mg-Si alloys were investigated using qualitative and quantitative aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF STEM). The needle-shaped β′-Ge precipitates are coherent with the Al matrix along the needle direction which is parallel to a 〈0 0 1〉 Al direction, as well as one direction in the cross-section plane that is parallel to a 〈1 0 0〉 Al direction. This is linked to a smaller lattice parameter in the needle cross-section plane than that of coarser, less coherent β′ precipitates in Al-Mg-Si alloys, despite Ge having a larger atomic radius than Si. Quantitative HAADF STEM results show that the nominal Ge columns of the β′-Ge precipitates are not fully occupied by Ge, the intensity of these columns being consistent with an Al concentration of 30 ± 10%, or a vacancy concentration of 20 ± 10%. The coherent interface is atomically smooth, but with matrix columns containing Ge spaced periodically along the interface.

Original languageEnglish (US)
Pages (from-to)3239-3246
Number of pages8
JournalActa Materialia
Volume60
Issue number6-7
DOIs
StatePublished - Apr 1 2012

Keywords

  • Aluminium alloys
  • High angle annular dark field
  • Precipitation
  • Scanning transmission electron microscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

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    Bjørge, R., Dwyer, C., Weyland, M., Nakashima, P. N. H., Marioara, C. D., Andersen, S. J., Etheridge, J., & Holmestad, R. (2012). Aberration-corrected scanning transmission electron microscopy study of β′-like precipitates in an Al-Mg-Ge alloy. Acta Materialia, 60(6-7), 3239-3246. https://doi.org/10.1016/j.actamat.2012.02.039