A passive lithium hydride based hydrogen generator for low power fuel cells for long-duration sensor networks

D. Strawser, J. Thangavelautham, S. Dubowsky

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

This paper focuses on developing an efficient fuel storage and release method for hydrogen using lithium hydride hydrolysis for use in PEM fuel cells for low power sensor network modules over long durations. Lithium hydride has high hydrogen storage density and achieves up to 95-100% yield. It is shown to extract water vapor freely from the air to generate hydrogen and has a theoretical fuel specific energy of up to 4900 Wh/kg. A critical challenge is how to package lithium hydride to achieve reaction completion. Experiments here show that thick layers of lithium hydride nearly chokes the reaction due to buildup of lithium hydroxide impeding water transport and preventing reaction completion. A model has been developed that describes this lithium hydride hydrolysis behavior. The model accurately predicts the performance of an experimental system than ran for 1400 h and consists of a passive lithium hydride hydrogen generator and PEM fuel cells. These results offer important design guidelines to enable reaction completion and build long-duration lithium hydride hydrogen generators for low power applications.

Original languageEnglish (US)
Pages (from-to)10216-10229
Number of pages14
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number19
DOIs
StatePublished - Jun 24 2014

Fingerprint

lithium hydrides
Hydrides
fuel cells
Sensor networks
Fuel cells
Lithium
generators
Hydrogen
sensors
hydrogen
hydrolysis
Hydrolysis
lithium hydroxides
chokes
Fuel storage
Electric inductors
Hydrogen storage
water vapor
Water vapor
modules

Keywords

  • Hydrogen generator
  • Hydrolysis
  • Lithium hydride
  • Passive control system
  • PEM
  • Sensor networks power supply

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

A passive lithium hydride based hydrogen generator for low power fuel cells for long-duration sensor networks. / Strawser, D.; Thangavelautham, J.; Dubowsky, S.

In: International Journal of Hydrogen Energy, Vol. 39, No. 19, 24.06.2014, p. 10216-10229.

Research output: Contribution to journalArticle

Strawser, D. ; Thangavelautham, J. ; Dubowsky, S. / A passive lithium hydride based hydrogen generator for low power fuel cells for long-duration sensor networks. In: International Journal of Hydrogen Energy. 2014 ; Vol. 39, No. 19. pp. 10216-10229.
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