Abstract

Green [1] and Swanson and Sinton [2] proposed two different approaches to predict the maximum obtainable fill factor (FF) from the open-circuit voltage (Voc) of a solar cell. This is convenient because the internal or implied open-circuit voltage of a solar cell can be measured at early stages of device processing (e.g., after passivation), giving rapid insight into expected device performance. However, these methods assume that recombination is linear in excess carrier density. In addition, both formulas also require that the ideality factor be known, and, while unity is often assumed, the ideality factor in fact varies with injection level. The expressions are often used in cases where these assumptions are clearly violated; here, we evaluate the accuracy in these cases. We find that the expressions are unable to predict the intrinsic FF generally, and their use must be restricted to very low or very high injection. We propose an alternative expression that is accurate for calculating the intrinsic-recombination-limited FF. With appropriate input parameters, e.g. wafer thickness, doping concentration and photogenerated current, the FF and Voc of solar cells can be predicted independent of each other. We investigate the accuracy of our proposed expression and see that its deviation from exact results are less than 0.3 % for FF and 1 mV for Voc.

Original languageEnglish (US)
Title of host publication2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)9781479979448
DOIs
StatePublished - Dec 14 2015
Event42nd IEEE Photovoltaic Specialist Conference, PVSC 2015 - New Orleans, United States
Duration: Jun 14 2015Jun 19 2015

Other

Other42nd IEEE Photovoltaic Specialist Conference, PVSC 2015
CountryUnited States
CityNew Orleans
Period6/14/156/19/15

Fingerprint

Silicon solar cells
Solar cells
Open circuit voltage
Passivation
Carrier concentration
Doping (additives)
Processing

Keywords

  • Fill factor
  • Green expression
  • Recombination
  • silicon

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Electronic, Optical and Magnetic Materials

Cite this

Leilaeioun, M., & Holman, Z. (2015). A new expression for intrinsic fill factor of silicon solar cells. In 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015 [7355950] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2015.7355950

A new expression for intrinsic fill factor of silicon solar cells. / Leilaeioun, Mehdi; Holman, Zachary.

2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc., 2015. 7355950.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Leilaeioun, M & Holman, Z 2015, A new expression for intrinsic fill factor of silicon solar cells. in 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015., 7355950, Institute of Electrical and Electronics Engineers Inc., 42nd IEEE Photovoltaic Specialist Conference, PVSC 2015, New Orleans, United States, 6/14/15. https://doi.org/10.1109/PVSC.2015.7355950
Leilaeioun M, Holman Z. A new expression for intrinsic fill factor of silicon solar cells. In 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc. 2015. 7355950 https://doi.org/10.1109/PVSC.2015.7355950
Leilaeioun, Mehdi ; Holman, Zachary. / A new expression for intrinsic fill factor of silicon solar cells. 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. Institute of Electrical and Electronics Engineers Inc., 2015.
@inproceedings{c464a035f51c438eabd61e5266e09861,
title = "A new expression for intrinsic fill factor of silicon solar cells",
abstract = "Green [1] and Swanson and Sinton [2] proposed two different approaches to predict the maximum obtainable fill factor (FF) from the open-circuit voltage (Voc) of a solar cell. This is convenient because the internal or implied open-circuit voltage of a solar cell can be measured at early stages of device processing (e.g., after passivation), giving rapid insight into expected device performance. However, these methods assume that recombination is linear in excess carrier density. In addition, both formulas also require that the ideality factor be known, and, while unity is often assumed, the ideality factor in fact varies with injection level. The expressions are often used in cases where these assumptions are clearly violated; here, we evaluate the accuracy in these cases. We find that the expressions are unable to predict the intrinsic FF generally, and their use must be restricted to very low or very high injection. We propose an alternative expression that is accurate for calculating the intrinsic-recombination-limited FF. With appropriate input parameters, e.g. wafer thickness, doping concentration and photogenerated current, the FF and Voc of solar cells can be predicted independent of each other. We investigate the accuracy of our proposed expression and see that its deviation from exact results are less than 0.3 {\%} for FF and 1 mV for Voc.",
keywords = "Fill factor, Green expression, Recombination, silicon",
author = "Mehdi Leilaeioun and Zachary Holman",
year = "2015",
month = "12",
day = "14",
doi = "10.1109/PVSC.2015.7355950",
language = "English (US)",
booktitle = "2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015",
publisher = "Institute of Electrical and Electronics Engineers Inc.",
address = "United States",

}

TY - GEN

T1 - A new expression for intrinsic fill factor of silicon solar cells

AU - Leilaeioun, Mehdi

AU - Holman, Zachary

PY - 2015/12/14

Y1 - 2015/12/14

N2 - Green [1] and Swanson and Sinton [2] proposed two different approaches to predict the maximum obtainable fill factor (FF) from the open-circuit voltage (Voc) of a solar cell. This is convenient because the internal or implied open-circuit voltage of a solar cell can be measured at early stages of device processing (e.g., after passivation), giving rapid insight into expected device performance. However, these methods assume that recombination is linear in excess carrier density. In addition, both formulas also require that the ideality factor be known, and, while unity is often assumed, the ideality factor in fact varies with injection level. The expressions are often used in cases where these assumptions are clearly violated; here, we evaluate the accuracy in these cases. We find that the expressions are unable to predict the intrinsic FF generally, and their use must be restricted to very low or very high injection. We propose an alternative expression that is accurate for calculating the intrinsic-recombination-limited FF. With appropriate input parameters, e.g. wafer thickness, doping concentration and photogenerated current, the FF and Voc of solar cells can be predicted independent of each other. We investigate the accuracy of our proposed expression and see that its deviation from exact results are less than 0.3 % for FF and 1 mV for Voc.

AB - Green [1] and Swanson and Sinton [2] proposed two different approaches to predict the maximum obtainable fill factor (FF) from the open-circuit voltage (Voc) of a solar cell. This is convenient because the internal or implied open-circuit voltage of a solar cell can be measured at early stages of device processing (e.g., after passivation), giving rapid insight into expected device performance. However, these methods assume that recombination is linear in excess carrier density. In addition, both formulas also require that the ideality factor be known, and, while unity is often assumed, the ideality factor in fact varies with injection level. The expressions are often used in cases where these assumptions are clearly violated; here, we evaluate the accuracy in these cases. We find that the expressions are unable to predict the intrinsic FF generally, and their use must be restricted to very low or very high injection. We propose an alternative expression that is accurate for calculating the intrinsic-recombination-limited FF. With appropriate input parameters, e.g. wafer thickness, doping concentration and photogenerated current, the FF and Voc of solar cells can be predicted independent of each other. We investigate the accuracy of our proposed expression and see that its deviation from exact results are less than 0.3 % for FF and 1 mV for Voc.

KW - Fill factor

KW - Green expression

KW - Recombination

KW - silicon

UR - http://www.scopus.com/inward/record.url?scp=84961644239&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84961644239&partnerID=8YFLogxK

U2 - 10.1109/PVSC.2015.7355950

DO - 10.1109/PVSC.2015.7355950

M3 - Conference contribution

BT - 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015

PB - Institute of Electrical and Electronics Engineers Inc.

ER -