A molecular beam optical/Stark study of calcium monoacetylide

A. J. Marr; J. Perry; Timothy Steimle

doi:10.1063/1.470038

A molecular beam optical/Stark study of calcium monoacetylide

A. J. Marr, J. Perry, Timothy Steimle

Molecular Sciences, School of (SMS)

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Abstract

A supersonic molecular beam optical Stark measurement of the Ã ²II_r-X̃²Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the X̃²Σ ⁺ and Ã²II_1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.

Original language	English (US)
Pages (from-to)	3861-3863
Number of pages	3
Journal	The Journal of chemical physics
Volume	103
Issue number	9
DOIs	https://doi.org/10.1063/1.470038
State	Published - 1995

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.470038

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@article{e683a42b5b0c4af0834d5d619bceeb61,

title = "A molecular beam optical/Stark study of calcium monoacetylide",

abstract = "A supersonic molecular beam optical Stark measurement of the {\~A} 2IIr-{\~X}2Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the {\~X}2Σ + and {\~A}2II1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.",

author = "Marr, {A. J.} and J. Perry and Timothy Steimle",

year = "1995",

doi = "10.1063/1.470038",

language = "English (US)",

volume = "103",

pages = "3861--3863",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "9",

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TY - JOUR

T1 - A molecular beam optical/Stark study of calcium monoacetylide

AU - Marr, A. J.

AU - Perry, J.

AU - Steimle, Timothy

PY - 1995

Y1 - 1995

N2 - A supersonic molecular beam optical Stark measurement of the Ã 2IIr-X̃2Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the X̃2Σ + and Ã2II1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.

AB - A supersonic molecular beam optical Stark measurement of the Ã 2IIr-X̃2Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the X̃2Σ + and Ã2II1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.

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U2 - 10.1063/1.470038

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 9

ER -

A molecular beam optical/Stark study of calcium monoacetylide

Abstract

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