A molecular beam optical/Stark study of calcium monoacetylide

A. J. Marr, J. Perry, Timothy Steimle

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Abstract

A supersonic molecular beam optical Stark measurement of the à 2IIr-X̃2Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the X̃2Σ + and Ã2II1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.

Original languageEnglish (US)
Pages (from-to)3861-3863
Number of pages3
JournalThe Journal of chemical physics
Volume103
Issue number9
DOIs
StatePublished - Jan 1 1995

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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