A molecular beam optical/Stark study of calcium monoacetylide

A. J. Marr, J. Perry, Timothy Steimle

Research output: Contribution to journal › Article

19 Citations (Scopus)

Abstract

A supersonic molecular beam optical Stark measurement of the à 2IIr-X̃2Σ band system of calcium monoacetylide CaCCH has been performed. The determined values of |μ| are 3.01 ±0.03 D and 2.41 ±0.02 D for the X̃2Σ + and Ã2II1/2 states, respectively. A simple electrostatic model quantitatively predicts the ground and excited state dipole moments.

Original languageEnglish (US)
Pages (from-to)3861-3863
Number of pages3
JournalThe Journal of Chemical Physics
Volume103
Issue number9
StatePublished - 1995

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Molecular beams
Dipole moment
Excited states
Ground state
molecular beams
calcium
Electrostatics
dipole moments
electrostatics
Calcium
ground state
excitation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

A molecular beam optical/Stark study of calcium monoacetylide. / Marr, A. J.; Perry, J.; Steimle, Timothy.

In: The Journal of Chemical Physics, Vol. 103, No. 9, 1995, p. 3861-3863.

Research output: Contribution to journal › Article

Marr, AJ, Perry, J & Steimle, T 1995, 'A molecular beam optical/Stark study of calcium monoacetylide', The Journal of Chemical Physics, vol. 103, no. 9, pp. 3861-3863.
Marr AJ, Perry J, Steimle T. A molecular beam optical/Stark study of calcium monoacetylide. The Journal of Chemical Physics. 1995;103(9):3861-3863.
Marr, A. J. ; Perry, J. ; Steimle, Timothy. / A molecular beam optical/Stark study of calcium monoacetylide. In: The Journal of Chemical Physics. 1995 ; Vol. 103, No. 9. pp. 3861-3863.
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