A microwave-optical double resonance spectroscopic study of TiO and TiN

Timothy Steimle, J. E. Shirley, K. Y. Jung, L. R. Russon, C. T. Scurlock

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

Original languageEnglish (US)
Pages (from-to)27-31
Number of pages5
JournalJournal of Molecular Spectroscopy
Volume144
Issue number1
DOIs
StatePublished - 1990

Fingerprint

Ground state
Microwaves
Spectroscopy
microwaves
Molecules
ground state
spectroscopy
molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

A microwave-optical double resonance spectroscopic study of TiO and TiN. / Steimle, Timothy; Shirley, J. E.; Jung, K. Y.; Russon, L. R.; Scurlock, C. T.

In: Journal of Molecular Spectroscopy, Vol. 144, No. 1, 1990, p. 27-31.

Research output: Contribution to journalArticle

Steimle, Timothy ; Shirley, J. E. ; Jung, K. Y. ; Russon, L. R. ; Scurlock, C. T. / A microwave-optical double resonance spectroscopic study of TiO and TiN. In: Journal of Molecular Spectroscopy. 1990 ; Vol. 144, No. 1. pp. 27-31.
@article{317a1d2a7a484db09f12b4afcb4826f2,
title = "A microwave-optical double resonance spectroscopic study of TiO and TiN",
abstract = "The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.",
author = "Timothy Steimle and Shirley, {J. E.} and Jung, {K. Y.} and Russon, {L. R.} and Scurlock, {C. T.}",
year = "1990",
doi = "10.1016/0022-2852(90)90305-A",
language = "English (US)",
volume = "144",
pages = "27--31",
journal = "Journal of Molecular Spectroscopy",
issn = "0022-2852",
publisher = "Academic Press Inc.",
number = "1",

}

TY - JOUR

T1 - A microwave-optical double resonance spectroscopic study of TiO and TiN

AU - Steimle, Timothy

AU - Shirley, J. E.

AU - Jung, K. Y.

AU - Russon, L. R.

AU - Scurlock, C. T.

PY - 1990

Y1 - 1990

N2 - The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

AB - The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO (X3Δ) and the N = 2 ← N = 1 pure rotational transition of TiN (X2Σ+) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels.

UR - http://www.scopus.com/inward/record.url?scp=0002841531&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002841531&partnerID=8YFLogxK

U2 - 10.1016/0022-2852(90)90305-A

DO - 10.1016/0022-2852(90)90305-A

M3 - Article

AN - SCOPUS:0002841531

VL - 144

SP - 27

EP - 31

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

SN - 0022-2852

IS - 1

ER -