A metal-organic framework with coordinatively unsaturated metal centers and microporous structure

Bin Mu; Yougui Huang; Krista S. Walton

doi:10.1039/c001485k

A metal-organic framework with coordinatively unsaturated metal centers and microporous structure

Bin Mu, Yougui Huang, Krista S. Walton

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel two dimensional porous framework [Cd₃(BTB) ₂(DEF)₄]_n·2nDEF (1) based on {Cd ₃} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N ₂ after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.

Original language	English (US)
Pages (from-to)	2347-2349
Number of pages	3
Journal	CrystEngComm
Volume	12
Issue number	8
DOIs	https://doi.org/10.1039/c001485k
State	Published - Aug 2010
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1039/c001485k

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title = "A metal-organic framework with coordinatively unsaturated metal centers and microporous structure",

abstract = "A novel two dimensional porous framework [Cd3(BTB) 2(DEF)4]n·2nDEF (1) based on {Cd 3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N 2 after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.",

author = "Bin Mu and Yougui Huang and Walton, {Krista S.}",

year = "2010",

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doi = "10.1039/c001485k",

language = "English (US)",

volume = "12",

pages = "2347--2349",

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publisher = "Royal Society of Chemistry",

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AU - Huang, Yougui

AU - Walton, Krista S.

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N2 - A novel two dimensional porous framework [Cd3(BTB) 2(DEF)4]n·2nDEF (1) based on {Cd 3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N 2 after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.

AB - A novel two dimensional porous framework [Cd3(BTB) 2(DEF)4]n·2nDEF (1) based on {Cd 3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N 2 after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.

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A metal-organic framework with coordinatively unsaturated metal centers and microporous structure

Abstract

ASJC Scopus subject areas

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