A Joint Structural Characterization of Colloidal Platinum by EXAFS and High‐Resolution Electron Microscopy

Daniel G. Duff, Peter P. Edwards, John Evans, J. Trevor Gauntlett, David A. Jefferson, Brian F G Johnson, Angus I. Kirkland, David Smith

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The accurate determination of lattice parameters of small colloidal Pt particles in solution can be accomplished by EXAFS analysis. Thus, it could be demonstrated that a lattice contraction (0.4 %) takes place in the transition from the metal to the colloidal state. The results of the EXAFS investigations supplement those obtained by high‐resolution electron microscopy (HREM). The diagram on the right shows a typical HREM photograph of a colloid particle with perfect cubic face centered lattice. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)590-593
Number of pages4
JournalAngewandte Chemie - International Edition
Volume28
Issue number5
DOIs
StatePublished - 1989

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Platinum
Electron microscopy
Colloids
Particles (particulate matter)
Lattice constants
Metals

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

A Joint Structural Characterization of Colloidal Platinum by EXAFS and High‐Resolution Electron Microscopy. / Duff, Daniel G.; Edwards, Peter P.; Evans, John; Gauntlett, J. Trevor; Jefferson, David A.; Johnson, Brian F G; Kirkland, Angus I.; Smith, David.

In: Angewandte Chemie - International Edition, Vol. 28, No. 5, 1989, p. 590-593.

Research output: Contribution to journalArticle

Duff, Daniel G. ; Edwards, Peter P. ; Evans, John ; Gauntlett, J. Trevor ; Jefferson, David A. ; Johnson, Brian F G ; Kirkland, Angus I. ; Smith, David. / A Joint Structural Characterization of Colloidal Platinum by EXAFS and High‐Resolution Electron Microscopy. In: Angewandte Chemie - International Edition. 1989 ; Vol. 28, No. 5. pp. 590-593.
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