A failure of continuum theory: Temperature dependence of the solvent reorganization energy of electron transfer in highly polar solvents

Chemical Compounds

• Reorganization Energy 100%
• Polar Solvent 80%
• Electron Transfer 56%
• Solvent 37%
• Dipole 14%
• Optical Transition 10%
• Dielectric Material 6%
• Sphere 6%
• Solute 6%
• Band Gap 5%
• Acetonitrile 5%
• Charge Transfer 5%

Physics & Astronomy

• electron transfer 81%
• continuums 58%
• temperature dependence 52%
• energy 23%
• dissection 19%
• dipoles 9%
• molecular theory 9%
• acetonitrile 8%
• translational motion 8%
• optical transition 7%
• solutes 6%
• temperature 5%
• charge transfer 5%
• slopes 5%
• shift 4%
• fluids 3%
• interactions 2%

Engineering & Materials Science

• Electrons 81%
• Temperature 32%
• Dissection 18%
• Optical transitions 14%
• Acetonitrile 10%
• Charge transfer 8%
• Energy transfer 7%
• Energy gap 7%
• Fluids 4%
• Experiments 2%