A Dual Catalyst with SERS Activity for Probing Stepwise Reduction and Oxidation Reactions

Jumei Li, Yiren Wu, Xiaojun Sun, Jingyue Liu, Sarah A. Winget, Dong Qin

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

Aromatic azo compounds are high-value chemicals extensively used as pigments, drugs, and food additives, but their production typically requires stoichiometric amounts of environmentally unfriendly metals or nitrites. There is an urgent need to develop a dual catalytic system capable of reducing nitroaromatics to aromatic amines, followed by their oxidation to azo compounds. Here we report such a dual catalyst based on Ag@Pd-Ag core-frame nanocubes for the stepwise conversion of 4-nitrothiophenol to trans-4,4′-dimercaptoazobenzene under ambient conditions. Our in situ surface-enhanced Raman spectroscopy study reveals three sequential processes that include the Pd-catalyzed reduction of 4-nitrothiophenol to 4-aminothiophenol by hydrogen, a period during which the 4-aminothiophenol remain unchanged until all hydrogen has depleted, and the Ag-catalyzed oxidation of 4-aminothiophenol to trans-4,4′-dimercaptoazobenzene by the O2 from air. This work will lead to an environmentally friendly and sustainable approach to the production of aromatic azo compounds.

Original languageEnglish (US)
Pages (from-to)786-790
Number of pages5
JournalChemNanoMat
Volume2
Issue number8
DOIs
StatePublished - Jan 1 2016

Keywords

  • Ag-catalyzed oxidation
  • bimetallic nanocrystals
  • catalysis
  • Pd-catalyzed reduction

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Biomaterials
  • Materials Chemistry

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