A μ-oxo mixed-metal complex of copper(II) and an iron(III)-porphyrin as a resting state model for the cytochrome c oxidase active site

Robert J. Saxton, Larry W. Olson, Lon J. Wilson

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

The complex (TPP)FeIV:O (TPP = tetraphenylporphyrin) reacts in solution with an imidazole-bearing CuI complex to form a stable mixed-metal μ-oxo-species, [Fe3+-O-Cu2+]+, as a resting state model compound for the binuclear active site of cytochrome c oxidase.

Original languageEnglish (US)
Pages (from-to)984-986
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
StatePublished - Jan 1 1982
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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