@article{9d1c2a34c8c847dfadfdc5fd1ee91bc7,
title = "A μ-oxo mixed-metal complex of copper(II) and an iron(III)-porphyrin as a resting state model for the cytochrome c oxidase active site",
abstract = "The complex (TPP)FeIV:O (TPP = tetraphenylporphyrin) reacts in solution with an imidazole-bearing CuI complex to form a stable mixed-metal μ-oxo-species, [Fe3+-O-Cu2+]+, as a resting state model compound for the binuclear active site of cytochrome c oxidase.",
author = "Saxton, {Robert J.} and Olson, {Larry W.} and Wilson, {Lon J.}",
note = "Funding Information: absorbances in the visible region at 552 (E = 1.30 x lo4)and 9 R. W. Shaw, J. E. Rife, M. H. O{\textquoteright}Leary, and H. Beinert, J. Biol. Chem., 1980, 256, 1105. 583 nm (E = 6.71 x 103).7 Even though [(TPP)Fe1l{\textquoteright}l20 would probably be a major impurity in (3), aboorbances in the 10 B. Chance and L. Powers, Biophvv. J., 1981, 33, 95a; L. visible spectrum at 571 and 610 nm corresponding to [(TPP) Powers, B. Chance, Y. Ching, and P. Angiolillo, Biophys. J., FellI],O are totally absent. 1981, 33, 95a. 11 S. E. Dcssens, C. L. Merrill, R. J. Saxton, R. L. Ilaria,L. J. W. thanks the Robert A. Welch Foundation and the R. L. Lindsay, and L. J. Wilson, J. Am. Chenz. Soc., in the U.S. N.S.F. and N.I.H. for support of this work. L. W. 0.also press.thanks the N.S.F. ",
year = "1982",
doi = "10.1039/C39820000984",
language = "English (US)",
pages = "984--986",
journal = "Journal of the Chemical Society, Chemical Communications",
issn = "0022-4936",
number = "17",
}